Quantitative Photophysics of Photoluminescent and Scintillating Nanoparticles

光致发光和闪烁纳米颗粒的定量光物理学

• 批准号: 312970-2013
• 负责人: Nadeau, Jay
• 金额: $ 3.81万
• 依托单位: McGill University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2013
• 资助国家: 加拿大
• 起止时间: 2013-01-01 至 2014-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=526627
• 关键词: Quantitative; Photophysics; Photoluminescent; Scintillating; Nanoparticles

Quantum dots (QDs) are fluorescent crystals of semiconductor materials (such as cadmium selenide, CdSe) that range from ~ 2 to 5 nm in diameter. This is less than 1/1000th the diameter of a typical living cell. QDs are capped with active molecules that enable them to remain in a stable suspension in water or other solutions. The energy and reactivity of QDs--determined by the material, capping agent, and size--determine the ability of a QD to transfer electrons to, or accept electrons from, other molecules in the solution. This electron transfer is very important for a large variety of applications and problems. Unwanted electron transfer can damage or kill biological tissue. Since it happens on the nanoscale, damage can occur deep inside cells, including the nucleus. On the other hand, electron transfer can be used to kill unwanted cells, such as cancer cells or bacteria. Transferring of electrons from QDs to other materials also allows QDs to be used as materials for solar cells, although currently the process is not well-enough understood to create high-efficiency materials.

量子点（QD）是半导体材料（例如硒化镉、CdSe）的荧光晶体，其直径范围为约2至5 nm。这是一个典型的活细胞直径的千分之一。量子点被活性分子覆盖，使它们能够在水或其他溶液中保持稳定的悬浮液。量子点的能量和反应性（由材料、封端剂和尺寸决定）决定了量子点将电子转移到溶液中的其他分子或从溶液中的其他分子接受电子的能力。这种电子转移对于各种各样的应用和问题是非常重要的。不需要的电子转移可以损伤或杀死生物组织。由于它发生在纳米级，损伤可能发生在细胞内部深处，包括细胞核。另一方面，电子转移可用于杀死不需要的细胞，如癌细胞或细菌。电子从量子点转移到其他材料也允许量子点被用作太阳能电池的材料，尽管目前对该过程的理解还不足以创造出高效材料。