New organometallic and coordination chemistry for the formation and activation of carbon-carbon bonds

用于碳-碳键形成和活化的新型有机金属和配位化学

基本信息

  • 批准号:
    138118-2011
  • 负责人:
  • 金额:
    $ 6.19万
  • 依托单位:
  • 依托单位国家:
    加拿大
  • 项目类别:
    Discovery Grants Program - Individual
  • 财政年份:
    2015
  • 资助国家:
    加拿大
  • 起止时间:
    2015-01-01 至 2016-12-31
  • 项目状态:
    已结题

项目摘要

Transition metal organometallic chemistry plays a critical role in many sectors of chemical technology. Metal-mediated organic reactions provide much of the methodology used for the development and commercial production of commodity and fine chemicals, in all industries dependent on organic synthesis and catalysis - pharmaceuticals, agricultural chemicals, polymers, and structural materials. The proposed research program is interdisciplinary, combining inorganic and organic chemistry to understand and manipulate the principles governing transition metal organometallic reactivity and function. Our approach might be described as engineering on a molecular level: the rational design and implementation of new metal-mediated organic reactions, both stoichiometric and catalytic. Our program impacts fundamental chemistry and practical applications, advancing our understanding of organometallic reaction mechanisms and introducing new transformations into organic synthesis and catalysis. This program provides a unique intellectual environment for training creative and productive young scientists, with the command and confidence necessary to solve serious research problems. Four specific investigations are proposed, ranging from new catalyst design to new strategies for the controlled cleavage of strong carbon-carbon bonds. First, new geometrically-constrained coordination complexes will be created and exploited for catalysis, with the metal(s) in strained coordination geometries. The three other projects involve the creation of new reactions in which complex organic molecules are made in a highly controlled fashion. The first expands on investigation of metal-directed radical alkylation, using metal coordination to invert natural selectivities. In the second project, new metal-mediated cycloaddition reactions will be developed for the preparation of important carbocyclic and heterocyclic materials. The third project is focused on new metal-directed ring-expansion reactions, an unusual process in which the metal cleaves open a carbon-carbon bond and inserts in a new two-carbon unit.
过渡金属有机金属化学在化工技术的许多领域起着至关重要的作用。金属介导的有机反应为所有依赖有机合成和催化的行业(药品、农业化学品、聚合物和结构材料)的商品和精细化学品的开发和商业化生产提供了许多方法。

项目成果

期刊论文数量(0)
专著数量(0)
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会议论文数量(0)
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Stryker, Jeffrey其他文献

Stryker, Jeffrey的其他文献

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{{ truncateString('Stryker, Jeffrey', 18)}}的其他基金

Hydrogen-free hydrogenolysis of strong C-S, C-O, and C-N bonds
强 C-S、C-O 和 C-N 键的无氢氢解
  • 批准号:
    RGPIN-2022-03282
  • 财政年份:
    2022
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
High-activity base metal catalysts for strong carbon-heteroatom bond activation
用于强碳-杂原子键活化的高活性贱金属催化剂
  • 批准号:
    RGPIN-2016-04848
  • 财政年份:
    2021
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
High-activity base metal catalysts for strong carbon-heteroatom bond activation
用于强碳-杂原子键活化的高活性贱金属催化剂
  • 批准号:
    RGPIN-2016-04848
  • 财政年份:
    2020
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
High-activity base metal catalysts for strong carbon-heteroatom bond activation
用于强碳-杂原子键活化的高活性贱金属催化剂
  • 批准号:
    RGPIN-2016-04848
  • 财政年份:
    2019
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
High-activity base metal catalysts for strong carbon-heteroatom bond activation
用于强碳-杂原子键活化的高活性贱金属催化剂
  • 批准号:
    RGPIN-2016-04848
  • 财政年份:
    2018
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
High-activity base metal catalysts for strong carbon-heteroatom bond activation
用于强碳-杂原子键活化的高活性贱金属催化剂
  • 批准号:
    RGPIN-2016-04848
  • 财政年份:
    2017
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
High-activity base metal catalysts for strong carbon-heteroatom bond activation
用于强碳-杂原子键活化的高活性贱金属催化剂
  • 批准号:
    RGPIN-2016-04848
  • 财政年份:
    2016
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
New organometallic and coordination chemistry for the formation and activation of carbon-carbon bonds
用于碳-碳键形成和活化的新型有机金属和配位化学
  • 批准号:
    138118-2011
  • 财政年份:
    2014
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
New organometallic and coordination chemistry for the formation and activation of carbon-carbon bonds
用于碳-碳键形成和活化的新型有机金属和配位化学
  • 批准号:
    138118-2011
  • 财政年份:
    2013
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
Novel catalysts for hydrodesulfurization and hydrodenitrogenation of heavy bitumen under mild conditions
温和条件下重质沥青加氢脱硫和加氢脱氮的新型催化剂
  • 批准号:
    415851-2011
  • 财政年份:
    2012
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Collaborative Research and Development Grants

相似国自然基金

功能有机配体新颖设计与有机金属超分子导向组装
  • 批准号:
    20772152
  • 批准年份:
    2007
  • 资助金额:
    28.0 万元
  • 项目类别:
    面上项目

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Organometallic and Coordination Chemistry Approaches to Small Molecule Activation Relevant to Renewable Energy and Resources
与可再生能源和资源相关的小分子活化的有机金属和配位化学方法
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New organometallic and coordination chemistry for the formation and activation of carbon-carbon bonds
用于碳-碳键形成和活化的新型有机金属和配位化学
  • 批准号:
    138118-2011
  • 财政年份:
    2014
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
New organometallic and coordination chemistry for the formation and activation of carbon-carbon bonds
用于碳-碳键形成和活化的新型有机金属和配位化学
  • 批准号:
    138118-2011
  • 财政年份:
    2013
  • 资助金额:
    $ 6.19万
  • 项目类别:
    Discovery Grants Program - Individual
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