Ultrafast terahertz dynamics of materials

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Many fundamental processes in nature occur over ultrafast time scales measured in picoseconds, or trillionths of a second. For example, in semiconductor materials like those used in computer chips and digital cameras, electrons can move freely in one direction for about a tenth of a picosecond before getting bumped in a different direction by small vibrations of the atoms. This scattering of electrons over such short time scales affects the flow of electrical current in materials. A pure semiconductor can actually be a good insulator, but absorption of light can generate both negative (electron) and positive (“hole”) charge carriers that are then free to move, making the material conducting. This phenomenon, which is called photoconductivity, forms the basis of most light sensing technologies. The photoexcited electrons and holes can move around inside the material for up to a few nanoseconds before becoming trapped at defect sites or emitting light as they recombine. In semiconductor nanomaterials, the lifetimes of photoexcited charge carriers can be tens of picoseconds, depending on the nanoscale morphology of the material.