Coordination complexes and polymers as photosensitizers and photocatalysts for solar energy conversion

配位络合物和聚合物作为太阳能转换的光敏剂和光催化剂

• 批准号: RGPIN-2018-05837
• 负责人: Hanan, Garry
• 金额: $ 4.66万
• 依托单位: Université de Montréal
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2018
• 资助国家: 加拿大
• 起止时间: 2018-01-01 至 2019-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=652990
• 关键词: Coordination; complexes; polymers; photosensitizers; photocatalysts

The rapidly growing concentration of carbon dioxide, CO2, in the Earth's atmosphere requires immediate attention on many levels: environmental, political, scientific and engineering. In 2016, the concentration of CO2 surged to a record high of 403.3 ppm, up from 400 ppm in 2015, according to the World Meteorological Organization (WMO): the largest single year increase seen in the last 30 years! In order to combat this trend and avoid a run-away greenhouse effect, my research program aims to convert sunlight into chemical energy that is non-carbon based, thus eliminating the addition of more greenhouse gases into our atmosphere. We will use polymers made from transition metal ions to capture sunlight and transfer electrons to Cobalt catalysts to produce hydrogen gas. The hydrogen will in turn be made available for use in fuel cells to eliminate our fossil fuel dependency. ***We have extensive expertise in the areas of transition metal chemistry and photochemistry, however, we are taking our research to the next level by also degrading noxious molecules. We will use these toxic compounds as a source of electrons for the photochemical production of hydrogen. For example, there is much interest in the petrochemical industry to eliminate dihydrogen sulfide, H2S, which is a by-product produced in the millions of tons per year by petroleum extraction and purification. The agriculture and forestry industries also produce immense quantities of biomass waste such as cellulose, lignin and ligno-cellulose. We will use H2S and biomass waste as a source of electrons for hydrogen production. Once we have completed our laboratory scale scientific studies, we will expand our research to use modern high through-put techniques such as flow reactors to be able to convert more biomass waste and H2S into hydrogen using only sunlight as the source of energy for this conversion. ***Four graduate students, one post-doctoral Fellow and one undergraduate will undertake this research and train in an area crucial to the future of Canada and the World. We will also receive several students from international laboratories to help in our efforts to curb the production of CO2 by producing hydrogen from sunlight. ***My research group has access to state-of-the-art equipment available at the Université de Montréal and the associated engineering school, Polytechnique. Each student and post-doctoral Fellow will learn a variety of skills, from standard purification and characterization techniques to more advanced techniques such as X-ray diffraction. They will also learn advanced computational methods such as Density Functional Theory to be able to calculate the properties of our target molecules before we prepare them in the laboratory. Thus, the personnel involved in this research program will be well-trained, well-mentored and perfectly prepared for employment opportunities in alternative energy research and development.

地球大气中二氧化碳二氧化碳二氧化碳浓度迅速增长需要在许多层面上立即关注：环境，政治，科学和工程。根据世界气象组织（WMO）的数据，2016年，二氧化碳的浓度升至创纪录的403.3 ppm，高于2015年的400 ppm：过去30年中最大的一年增长！为了应对这一趋势并避免逃亡的温室效应，我的研究计划旨在将阳光转化为非碳基化学能，从而消除了在我们的大气中增加更多温室气体的添加。我们将使用通过过渡金属离子制成的聚合物来捕获阳光并将电子传递到钴催化剂以产生氢气。氢将又可以用于燃料电池中，以消除我们的化石燃料依赖性。 ***我们在过渡金属化学和光化学领域拥有广泛的专业知识，但是，我们正在通过降低有害分子来将研究提升到一个新的水平。我们将使用这些有毒化合物作为氢的光化学生产的电子来源。例如，对石化工业有很大的兴趣消除硫化二氢H2S，这是通过石油提取和纯化每年在数百万吨中生产的副产品。农业和林业产业还产生了大量的生物量废物，例如纤维素，木质素和木质纤维素。我们将使用H2S和生物量废物作为氢生产的电子来源。一旦完成了实验室规模的科学研究，我们将扩大研究，以使用现代的高贯穿技术，例如流动反应器，以便能够将更多的生物质废物和H2S转换为氢，仅使用阳光作为这种转换的能量来源。 ***四名研究生，一名博士后研究员和一名本科生将进行这项研究，并在对加拿大和世界的未来至关重要的地区进行培训。我们还将收到来自国际实验室的几名学生，以帮助我们通过从阳光中生产氢来遏制二氧化碳的生产。 ***我的研究小组可以访问蒙特利尔大学和相关工程学校Polytechnique的最先进设备。每个学生和博士后研究员将学习各种技能，从标准纯化和表征技术到更先进的技术，例如X射线衍射。他们还将学习先进的计算方法，例如密度功能理论，以便在我们在实验室中做好准备之前，能够计算目标分子的特性。这是该研究计划的参与人员将是训练有素，经过良好的训练有素，并为替代能源研发的就业机会做好了准备。