Investigation of metal-organic frameworks for electrocatalytic CO2 reduction

电催化 CO2 还原的金属有机框架研究

• 批准号: 571209-2021
• 负责人: Kornienko, Nikolay
• 金额: $ 1.82万
• 依托单位: Université de Montréal
• 依托单位国家: 加拿大
• 项目类别: Alliance Grants
• 财政年份: 2021
• 资助国家: 加拿大
• 起止时间: 2021-01-01 至 2022-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=729071
• 关键词: Investigation; metal; organic; frameworks; electrocatalytic

This project aims to investigate catalysts for the electrochemical reduction of CO2 to fuels. CO2 capture from factory emissions or via direct air capture and its subsequent conversion to renewable fuels via electrosynthesis is expected to play an increasingly significant role in Canada's renewable energy and sustainability efforts, as outlined in the Hydrogen Strategy for Canada. To this end, the proposed work combines the synthetic expertise from Dr. Roy's lab in the University of Lincoln (UNL) with the spectroscopic capacity at Prof. Kornienko's lab at the University of Montreal (UdeM) to investigate a metal-organic-framework (MOF) electrocatalyst that can be rationally tuned at a molecular level to maximize its activity.Importantly, this project combines fundamental chemical insights with industrially applicability that is expected to lead to substantial growth on the academic and industrial fronts in Canada and the United Kingdom as both countries' renewable energy investment grows and they take positions of leadership in the global push for sustainability. The collaboration here is critical because the takes advantage of the Roy lab's unique synthetic expertise in synthesizing electroactive MOF materials with the Kornienko Lab's one-of-a-kind in situ spectroscopic tools that would enable a mechanistic investigation of the MOFs. Both PIs leading this project have a deep base of expertise in their respective sub-fields and are at the beginning of their independent careers, indicating that there is much room to grow the collaboration upon the completion of the initial project. HQPs involved will receive a broad scientific training and to render them ready for a next step in both academia and in a host of industries (ex. Battery, pharma, analytical chemistry...).In sum, this proposed project draws from unique scientific capacities from UdeM and UNL to launch a collaboration that will implement a new paradigm in P2X technologies to help propel Canada and UK as leaders in renewable energy.

该项目旨在研究用于电化学还原CO2为燃料的催化剂。如《加拿大氢战略》所述，从工厂排放物或通过直接空气捕集二氧化碳并随后通过电合成将其转化为可再生燃料，预计将在加拿大的可再生能源和可持续性努力中发挥越来越重要的作用。为此，拟议的工作将林肯大学（UNL）Roy博士实验室的合成专业知识与蒙特利尔大学（UdeM）Kornienko教授实验室的光谱能力相结合，以研究金属有机框架（MOF）电催化剂，该催化剂可以在分子水平上合理调整以最大限度地提高其活性。该项目将基础化学知识与工业实用性相结合，预计将导致加拿大和英国在学术和工业方面的大幅增长，因为这两个国家的可再生能源投资增长，他们采取了以下立场：在全球推动可持续发展方面发挥领导作用。这里的合作是至关重要的，因为利用罗伊实验室在合成电活性MOF材料方面的独特合成专业知识，以及科尔尼延科实验室独一无二的原位光谱工具，可以对MOF进行机械研究。 领导该项目的两位PI在各自的子领域都有深厚的专业知识基础，并且正处于独立职业生涯的开始阶段，这表明在初始项目完成后，合作还有很大的发展空间。参与的HQP将接受广泛的科学培训，并使他们为学术界和许多行业的下一步做好准备。电池、制药、分析化学.）。总而言之，这个拟议的项目利用UdeM和UNL独特的科学能力，发起一项合作，将在P2X技术中实施一种新的范式，以帮助推动加拿大和英国成为可再生能源的领导者。