Supramolecular Chemistry And Functional Materials

超分子化学与功能材料

• 批准号: CRC-2014-00074
• 负责人: Loeb, Stephen
• 金额: $ 14.57万
• 依托单位: University of Windsor
• 依托单位国家: 加拿大
• 项目类别: Canada Research Chairs
• 财政年份: 2021
• 资助国家: 加拿大
• 起止时间: 2021-01-01 至 2022-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=729485
• 关键词: Supramolecular; Chemistry; Functional; Materials

A new synthetic methodology will be developed for the preparation of crystalline solid state materials known as metal-organic frameworks (MOFs). This protocol will be used to create MOFs with unique structural features, properties and applications. Some examples include: 1) ultra-high, porosity for gas storage, 2) flexible frameworks to act as sponge-like storage materials for sorption of small molecules, 3) easily accessible, sites to insert reactive metal centres for catalysis and 4) cavities imprinted with enough free volume to allow large amplitude motion and the creation of solid-state, molecular switches.

一种新的合成方法将被开发用于制备被称为金属有机框架（mof）的晶体固态材料。该协议将用于创建具有独特结构特征、属性和应用的mof。一些例子包括：1)超高孔隙度，用于气体储存；2)灵活的框架，作为海绵状存储材料，用于吸附小分子；3)易于访问，插入活性金属中心进行催化；4)具有足够自由体积的腔体，允许大振幅运动和创建固态分子开关。