Transformations of adamantyls and other molecular nanodiamonds in the coordination sphere of metals
金刚烷基和其他分子纳米金刚石在金属配位层中的转变
基本信息
- 批准号:RGPIN-2021-02620
- 负责人:
- 金额:$ 1.75万
- 依托单位:
- 依托单位国家:加拿大
- 项目类别:Discovery Grants Program - Individual
- 财政年份:2022
- 资助国家:加拿大
- 起止时间:2022-01-01 至 2023-12-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
Consider a diamond. We want to focus on its atomic structure and want to explore the question of which materials we could obtain if we could synthesize at will selected fragments of its extended 3D structure. We could desire to make, for example, a diamond membrane that is just two carbon atoms thick, an exceptionally strong and clear membrane. Although a name for such a membrane exists (digraphane), nobody knows how to make this membrane, which is related to graphene (Nobel Prize 2010) but vastly different in its properties. Or a three-dimensional nano-structure that is rigid, well-defined, bio-compatible, and made from five or more conjoined adamantane (the smallest diamond) cages. Nobody knows how to make this either. Or a very strong fiber made from diamond, as thin as maintaining the diamond structure allows. We are not able yet to create such a fiber. There is a world of possible materials, many having highly desirable properties, in the incredibly large realm bordered by macroscopic diamond one one side and the smallest possible diamond, adamantane, on the other side. How to synthesize the wealth of materials in this realm is almost completely unknown. The Fekl group is exploring the use of metals as mediators and catalysts, for new synthesis approaches in the difficult and important field of nano-diamond-based chemistry. The research involves connecting metals to a specific position of the smallest nano-diamond (the adamantane mentioned above) and then using reactions that only metals can accomplish to open up vast possibilities for making new compounds and materials. Spin-offs from this research will be new methods for the synthesis of pharmaceuticals such as antivirals, as well as new catalysts that aid our ability to produce a large variety of useful compounds.
想想钻石。我们想把重点放在它的原子结构上,并想探索如果我们可以随意合成它的扩展3D结构的选定片段,我们可以获得哪些材料。例如,我们可能希望制造一种只有两个碳原子厚的金刚石膜,一种异常坚固且透明的膜。虽然这种膜有一个名字(digraphane),但没有人知道如何制造这种膜,它与石墨烯(2010年诺贝尔奖)有关,但性质截然不同。或者是一个三维纳米结构,它是刚性的,定义明确的,生物相容的,由五个或更多个相连的金刚烷(最小的金刚石)笼制成。也没人知道怎么做这个。或者是由金刚石制成的非常坚固的纤维,尽可能薄地保持金刚石结构。我们还不能制造出这样的纤维。有一个可能的材料的世界,许多具有非常理想的特性,在令人难以置信的大领域中,一边是宏观金刚石,另一边是最小的金刚石,金刚烷。如何合成这个领域的丰富材料几乎是完全未知的。Fekl小组正在探索使用金属作为介体和催化剂,用于纳米金刚石化学这一困难而重要的领域的新合成方法。该研究涉及将金属连接到最小的纳米金刚石(上面提到的金刚烷)的特定位置,然后使用只有金属才能完成的反应来开辟制造新化合物和材料的巨大可能性。这项研究的副产品将是合成抗病毒药物等药物的新方法,以及帮助我们生产各种有用化合物的新催化剂。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Fekl, Ulrich其他文献
Tuning of the Spin Distribution between Ligand- and Metal-Based Spin: Electron Paramagnetic Resonance of Mixed-Ligand Molybdenum Tris(dithiolene) Complex Anions
- DOI:
10.1021/ic201047k - 发表时间:
2011-09-19 - 期刊:
- 影响因子:4.6
- 作者:
Fekl, Ulrich;Sarkar, Biprajit;Neilson Nguyen - 通讯作者:
Neilson Nguyen
Ligand-Based Reactivity of a Platinum Bisdithiolene: Double Diene Addition Yields a New C2-Chiral Chelate Ligand
- DOI:
10.1021/ic901116c - 发表时间:
2009-10-05 - 期刊:
- 影响因子:4.6
- 作者:
Kerr, Mitchell J.;Harrison, Daniel J.;Fekl, Ulrich - 通讯作者:
Fekl, Ulrich
Why Diorganyl Zinc Lewis Acidity Dramatically Increases with Narrowing C-Zn-C Bond Angle
- DOI:
10.1021/acs.inorgchem.9b02193 - 发表时间:
2020-03-02 - 期刊:
- 影响因子:4.6
- 作者:
Mirabi, Bijan;Poh, Wei Church;Fekl, Ulrich - 通讯作者:
Fekl, Ulrich
Adamantyl metal complexes: new routes to adamantyl anions and new transmetallations
- DOI:
10.1039/c7dt00428a - 发表时间:
2017-05-21 - 期刊:
- 影响因子:4
- 作者:
Armstrong, David;Taullaj, Fioralba;Fekl, Ulrich - 通讯作者:
Fekl, Ulrich
Fekl, Ulrich的其他文献
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{{ truncateString('Fekl, Ulrich', 18)}}的其他基金
Transformations of adamantyls and other molecular nanodiamonds in the coordination sphere of metals
金刚烷基和其他分子纳米金刚石在金属配位层中的转变
- 批准号:
RGPIN-2021-02620 - 财政年份:2021
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Understanding and Exploiting Transition Metal Complexes with Redox-active Ligands
了解和利用具有氧化还原活性配体的过渡金属配合物
- 批准号:
RGPIN-2016-05599 - 财政年份:2020
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Understanding and Exploiting Transition Metal Complexes with Redox-active Ligands
了解和利用具有氧化还原活性配体的过渡金属配合物
- 批准号:
RGPIN-2016-05599 - 财政年份:2019
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Understanding and Exploiting Transition Metal Complexes with Redox-active Ligands
了解和利用具有氧化还原活性配体的过渡金属配合物
- 批准号:
RGPIN-2016-05599 - 财政年份:2018
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Understanding and Exploiting Transition Metal Complexes with Redox-active Ligands
了解和利用具有氧化还原活性配体的过渡金属配合物
- 批准号:
RGPIN-2016-05599 - 财政年份:2017
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Understanding and Exploiting Transition Metal Complexes with Redox-active Ligands
了解和利用具有氧化还原活性配体的过渡金属配合物
- 批准号:
RGPIN-2016-05599 - 财政年份:2016
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Transition Metal Complexes with Redox-active Ligands: Understanding and Using Unusual Electronic Structures and Ligand-based reactivity
具有氧化还原活性配体的过渡金属配合物:理解和使用不寻常的电子结构和基于配体的反应性
- 批准号:
298376-2010 - 财政年份:2014
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Transition Metal Complexes with Redox-active Ligands: Understanding and Using Unusual Electronic Structures and Ligand-based reactivity
具有氧化还原活性配体的过渡金属配合物:理解和使用不寻常的电子结构和基于配体的反应性
- 批准号:
298376-2010 - 财政年份:2013
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Transition Metal Complexes with Redox-active Ligands: Understanding and Using Unusual Electronic Structures and Ligand-based reactivity
具有氧化还原活性配体的过渡金属配合物:理解和使用不寻常的电子结构和基于配体的反应性
- 批准号:
298376-2010 - 财政年份:2012
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Transition Metal Complexes with Redox-active Ligands: Understanding and Using Unusual Electronic Structures and Ligand-based reactivity
具有氧化还原活性配体的过渡金属配合物:理解和使用不寻常的电子结构和基于配体的反应性
- 批准号:
298376-2010 - 财政年份:2011
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
相似海外基金
Transformations of adamantyls and other molecular nanodiamonds in the coordination sphere of metals
金刚烷基和其他分子纳米金刚石在金属配位层中的转变
- 批准号:
RGPIN-2021-02620 - 财政年份:2021
- 资助金额:
$ 1.75万 - 项目类别:
Discovery Grants Program - Individual
Metal Adamantyls
金属金刚烷
- 批准号:
527147-2018 - 财政年份:2018
- 资助金额:
$ 1.75万 - 项目类别:
University Undergraduate Student Research Awards
Metal Adamantyls
金属金刚烷
- 批准号:
498200-2016 - 财政年份:2016
- 资助金额:
$ 1.75万 - 项目类别:
University Undergraduate Student Research Awards
Metal Adamantyls
金属金刚烷
- 批准号:
466150-2014 - 财政年份:2014
- 资助金额:
$ 1.75万 - 项目类别:
University Undergraduate Student Research Awards