Nanoparticle interactions with swollen polymer networks

纳米粒子与膨胀聚合物网络的相互作用

• 批准号: RGPIN-2020-05162
• 负责人: Hill, Reghan
• 金额: $ 2.84万
• 依托单位: McGill University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2022
• 资助国家: 加拿大
• 起止时间: 2022-01-01 至 2023-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=747142
• 关键词: Nanoparticle; interactions; swollen; polymer; networks

Hydrogels are soft polymer networks that take on striking amounts of water, making them highly porous to molecules-similarly to liquid water-but with solid-like mechanical properties. They are used in a vast range of domestic and industrial applications, including food, cosmetics, medicine, agriculture, and enhanced oil recovery. While hydrogel properties are often tailored to specific applications via polymer chemistry, another approach is to modify the microstructure using nanoparticles, thus forming ``hydrogel nano-composites''. The motivation may be to reduce costs, particularly for large-scale industrial applications, or to achieve very specific properties for niche applications. However, nanoparticle doping brings with it a plethora of new practical and fundamental scientific challenges. These arise from the complicated and poorly understood manner in which nanoparticles interact with cross-linked polymer networks. The proposed research will tackle several fundamental scientific challenges-using theoretical, computational, and experimental methodologies-that will help to address important industrial and societal questions arising from nanoparticle use in hydrogel technologies. Envisioned is a ``diagnostic toolbox''-featuring electroacoustic, dielectric and rheological spectroscopy-and a nanoparticle assay to unambiguously quantify how nanoparticles interact with hydrogel networks. The mechanistic insights required to develop and apply this platform-in advanced-materials, environmental, and human-health fields-will be sought in the next five years by integrating (i) experimental model systems, (ii) novel applications of elactro-acoustic, dielectric and rheological spectroscopy, (iii) continuum-scale computation, and (iv) molecular-scale simulation. This program of research will generate fundamental knowledge to strengthen Canada's advanced materials and bio-technology industries, provide rigorous scientific input on nanoparticle release, transport and human-health concerns, and empower a new generation of engineers with expert knowledge and practical expertise for industrial and academic leadership.

水凝胶是一种柔软的聚合物网络，它能吸收大量的水，使其具有高度的分子多孔性--类似于液态水--但具有类似固体的机械性能。它们用于广泛的家庭和工业应用，包括食品，化妆品，医药，农业和提高石油采收率。虽然水凝胶的特性通常通过聚合物化学来适应特定的应用，但另一种方法是使用纳米颗粒来改变微结构，从而形成“水凝胶纳米复合材料”。其动机可能是降低成本，特别是对于大规模工业应用，或为利基应用实现非常特定的特性。然而，纳米粒子掺杂带来了大量新的实践和基础科学挑战。这些问题源于纳米颗粒与交联聚合物网络相互作用的复杂且人们知之甚少的方式。拟议的研究将解决几个基本的科学挑战-使用理论，计算和实验方法-这将有助于解决重要的工业和社会问题所产生的纳米粒子在水凝胶技术中的使用。设想是一个“诊断工具箱”-具有电声，介电和流变光谱-和纳米颗粒测定明确量化纳米颗粒如何与水凝胶网络相互作用。在未来五年内，将通过整合（i）实验模型系统，（ii）电声，介电和流变光谱的新应用，（iii）连续尺度计算和（iv）分子尺度模拟来寻求开发和应用该平台所需的机械见解。该研究计划将产生基础知识，以加强加拿大的先进材料和生物技术产业，为纳米颗粒的释放，运输和人类健康问题提供严格的科学投入，并为新一代工程师提供专业知识和实用专业知识，以促进工业和学术领导。