硅铝质玻璃体是多种大宗工业废渣的主要成分，提升其水化活性以增强胶凝能力是提升水泥工业消纳工业废渣效率的关键技术。项目针对外掺五配位铝改性C-A-S-H凝胶分子和纳微结构并提升硅铝质玻璃体水化效率的微观机理这一基础理论问题，以超原子材料Keggin-Al13为创新改性材料，面向硅铝质玻璃体水化活性提升的目标，从Keggin-Al13水解过程和产物性状研究出发，运用NMR、XPS、FE-SEM、SPM等多种先进技术论证水解五配位铝改性C-A-S-H凝胶结构的微观机制，论证C-A-S-H凝胶结构与其离子传输能力的关系，揭示凝胶性质与玻璃体溶蚀过程的理论联系，发展硅铝质玻璃体水化效率强化和胶凝性能提升的新理论。项目研究采用新材料改造传统水泥基材料，发展一种全新的含工业废渣水泥胶凝性能提升理论，并成为水泥化学和混凝土科学新增知识点。

Aluminosilicate glass is the main composition of many industrial wastes with large volumes. Promoting its hydraulic reactivity and enhancing its binding performance is the key technology for consuming capacities of cement industry to industrial wates. The project is aimed at the fundamental theory on promoting the hydraulic efficiency of aluminosilcate glass by adding five-coordinated aluminum that modifies the molecular and nano-micro structure of the C-A-S-H gel, by using the superatom material Keggin-Al13 as the innovative modification materails for the target of promoting the hydraulic reactivity of glass. The research starts with analysis on the hydrolysis process and properties of the products of Keggin-Al13, uses advanced techniques including NMR, XPS, FE-SEM and SPM to investigate the microstructural modification mechanism of five-coordinated aluminum to the structure of C-A-S-H gel, to study the relation between the transport capabability of C-A-S-H gel and its structure, and to establish the theoretical links between the gel properties and the corrosion process of glass. A new theory on promoting the hydraulic efficiency and enhancing the binding performance of aluminosilicate glass will be established. The research uses new material to modify the traditional cementitious materials, develops a new theory on promoting the binding performance of cement containing industrial wastes, and adds to the knowledge on cement chemistry and concrete science.