气流床气化炉内耐火砖分区侵蚀特性及蚀损机理研究

批准号:
21878094
项目类别:
面上项目
资助金额:
60.0 万元
负责人:
龚岩
依托单位:
学科分类:
B0815.能源化工
结题年份:
2022
批准年份:
2018
项目状态:
已结题
项目参与者:
许建良、沈中杰、刘霞、薛志村、祝慧雯、何磊、马雅诗、王嘉剑、杨家宝
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中文摘要
气流床煤气化是煤炭清洁高效转化的核心技术,是发展煤基化学品、液体燃料合成、制氢等过程工业的基础,是煤炭气化重要发展方向,气流床气化炉是实现气化过程的核心设备和载体。耐火砖作为气流床气化炉最重要的组成元素之一,起到隔温、蓄热和流场约束等作用,在构建气化炉内有效空间的同时,又受到高温气流、颗粒和熔渣的冲刷和侵蚀,工作环境恶劣。本项目基于气流床气化热态试验平台,通过炉内可视化及算法重建热态气化炉耐火砖壁面三维温度场,辅以炉内高速成像技术探究颗粒及熔渣壁面沉积和侵蚀过程特性,开展用后试验气化炉和工业气化炉耐火砖宏观及微观结构的对比剖析、表征和统计分析,结合炉内气相、颗粒相流场结构、温度场数值模拟及热力学计算结果,共同揭示气化过程耐火砖物理、化学侵蚀特性及规律,构建系统的全炉膛耐火砖分区蚀损机理模型,服务于新型耐火砖结构和新材料的开发、超大规模清洁高效气化炉的优化设计及气化系统的长周期安全稳定运行。
英文摘要
As a key technology of coal gasification, entrained-flow gasification is one of the core technologies for clean and high efficiency utilizing of coal, and is the basis for developing coal-based industries, such as chemical products, liquid fuel, hydrogen production, etc., while entrained-flow gasifier can be an effective equipment or reactor for realizing gasification process. Refractory plays an important role in gasifier, it isolates and accumulates heat, constructs working space and constrains flow field in gasifier. As a result, refractory is serving under severe conditions and suffering from high temperature gas, particles and slag, which cause corrosion and erosion. Based on a bench-scale opposed multi-burner gasification platform, the three-dimensional temperature distribution of refractory under hot model condition is reconstructed by on-site visualization techniques and temperature reconstruction algorithm in gasifier, while the high speed imaging is applied to investigate the particle/slag deposition and erosion characteristics on refractory. The after used refractory from both bench-scale gasifier and industrial gasifier are analyzed and compared under macro and micro scale for obtaining superficial characteristics and statistical results, which are coupled with numerical simulation of particle flow field structure and three-dimensional temperature distribution as well as thermodynamic simulation, in order to reveal the erosion and corrosion characteristics, statistical law and full-gasifier refractory subarea failure mechanism of refractory. The results of this research would be applied for the development of new type of refractory structure as well as refractory material, the optimization design of ultra-scale clean and efficient industrial gasifier, and the long period, security and steady operation of the whole gasification system.
气流床煤气化是煤炭清洁高效转化的核心技术,是发展煤基化学品、液体燃料合成、制氢等过程工业的基础,是煤炭气化重要发展方向,气流床气化炉是实现气化过程的核心设备和载体。耐火砖作为气流床气化炉最重要的组成元素之一,起到隔温、蓄热和流场约束等作用,在构建气化炉内有效空间的同时,又受到高温气流、颗粒和熔渣的冲刷和侵蚀,工作环境恶劣。本项目基于气流床气化热态试验平台,通过炉内可视化及算法重建热态气化炉耐火砖壁面三维温度场,辅以炉内高速成像技术探究颗粒及熔渣壁面沉积和侵蚀过程特性,开展用后试验气化炉和工业气化炉耐火砖宏观及微观结构的对比剖析、表征和统计分析,结合炉内气相、颗粒相流场结构、温度场数值模拟及热力学计算结果,共同揭示气化过程耐火砖物理、化学侵蚀特性及规律,构建系统的全炉膛耐火砖分区蚀损机理模型,服务于新型耐火砖结构和新材料的开发、超大规模清洁高效气化炉的优化设计及气化系统的长周期安全稳定运行。
期刊论文列表
专著列表
科研奖励列表
会议论文列表
专利列表
Corrosion of phosphate added high-chrome refractory materials in an entrained-flow gasifier
添加磷酸盐的高铬耐火材料在气流床气化炉中的腐蚀
DOI:10.1016/j.ceramint.2022.01.271
发表时间:2022-02
期刊:Ceramics International
影响因子:5.2
作者:Kuiyu Liu;Qinghua Guo;Xu Fang;Abdul Raheem;Yan Gong;Hongxia Li;Guangsuo Yu
通讯作者:Guangsuo Yu
Corrosion of high-chrome refractory materials by high-sodium slag in an entrained-flow gasifier
气流床气化炉中高钠渣对高铬耐火材料的腐蚀
DOI:10.1016/j.ceramint.2021.07.242
发表时间:2021-07
期刊:Ceramics International
影响因子:5.2
作者:Kuiyu Liu;Qinghua Guo;Yan Gong;Xueli Chen;Tao Wu;Shuai Wang;Guangsuo Yu
通讯作者:Guangsuo Yu
Effects of phosphate additives on the wetting and corrosion resistance of high-chrome refractory materials to two slags
磷酸盐添加剂对高铬耐火材料对两种炉渣润湿及耐腐蚀性的影响
DOI:10.1016/j.ceramint.2022.10.339
发表时间:2022-10
期刊:Ceramics International
影响因子:5.2
作者:Kuiyu Liu;Qinghua Guo;Abdul Raheem;Yan Gong;Jinye Mo;Hongxia Li;Guangsuo Yu
通讯作者:Guangsuo Yu
Refractory failure in entrained-flow gasifier: Investigation of partitioned erosion characteristics in an industrial opposed multi-burner gasifier
气流床气化炉耐火材料失效:工业对置多燃烧器气化炉分区侵蚀特性研究
DOI:10.1016/j.ces.2019.115227
发表时间:2019-12-31
期刊:CHEMICAL ENGINEERING SCIENCE
影响因子:4.7
作者:Gong, Yan;Guo, Qinghua;Yu, Guangsuo
通讯作者:Yu, Guangsuo
Corrosion in high alumina refractory serviced in a bench-scale entrained flow gasifier
小型气流床气化炉中使用的高铝耐火材料的腐蚀
DOI:10.1016/j.ceramint.2020.09.061
发表时间:2021-01
期刊:Ceramics International
影响因子:5.2
作者:Shuai Wang;Qinghua Guo;Yan Gong;Shuhong Liao;Lingling Bao;Guangsuo Yu
通讯作者:Guangsuo Yu
基于电-磁耦合火焰调控机理的耐火衬里延寿研究
- 批准号:--
- 项目类别:省市级项目
- 资助金额:0.0万元
- 批准年份:2025
- 负责人:龚岩
- 依托单位:
基于炉膛可视化的多喷嘴对置式水煤浆气化炉内颗粒特性及反应机理研究
- 批准号:51406056
- 项目类别:青年科学基金项目
- 资助金额:20.0万元
- 批准年份:2014
- 负责人:龚岩
- 依托单位:
国内基金
海外基金
