为提高材料的载流子分离效率与可见光催化活性，本课题拟利用水热法与液相还原法快速构建暴露{101}面自掺杂TiO2纳米片薄膜光电极。通过透射电子显微镜、X-射线光电子能谱、电子自旋共振以及时间分辨表面光电压谱等测试揭示暴露{101}面自掺杂TiO2纳米片薄膜光电极微观形貌结构-表面化学形态-载流子分离效率-光催化活性之间的内在关联，并阐明其形成机制与可见光催化活性提高机理。通过研究反应体系中药品及个人护理品在暴露{101}面自掺杂TiO2纳米片薄膜光电极表面的吸附和降解行为，探究不同影响因素与活性物种对其可见光催化效率的作用规律，归纳出相应的光催化降解模型与动力学方程，解析其对水中药品及个人护理品的光催化降解机理，为高效去除水中新兴污染物的水净化环境功能材料的设计与开发提供切实可行的策略，为光催化技术的工业化提供技术支持。本项目拟采用的合成策略具有操作简单、反应迅速且容易放大合成等特点。

In order to improve the visible light photocatalytic (PC) performance and separation efficiency of photogenerated charge carriers of materials, self-doped TiO2 nanosheets films (STNSFs) photoelectrodes with exposed{101} facets were rapidly fabricated by integration hydrothermal method and solution reduction strategy. Subsequently, the intrinsic relationships among micro morphology and structure, surface chemical states, separation efficiency of photogenerated charge carriers, and PC performance of the STNSFs photoelectrodes with exposed {101} facets were investigated through transmission electron microscope, X-ray photoelectron spectroscopy, electron spin resonance and time-resolved surface photovoltage spectrum techniques. Meanwhile, both the formation principle and enhanced visible light PC mechanism were clarified. Based on the adsorption and decomposition behaviors of pharmaceutical and personal care products(PPCPs) in the reaction system on the surface of the STNSFs photoelectrodes with exposed {101} facets, the effects of different parameters and reactive species on the visible light PC efficiencies were explored. Furthermore, the corresponding models and kinetic equations of PC degradations were concluded, as well as the PC mechanism for the degradation of PPCPs in water, which could provide a feasible strategy for the design and development of environment-friendly functional materials for emerging contaminants containing wastewater purification. In addition, the high PC efficiency for the removal of PPCPs in water could also provide technical support for the industrialized application. The synthetic strategy in this project possesses the characteristics of simple-operation, fast-reaction and easy enlarged synthesis.