矿物掺合料能显著改善混凝土材料工作性与耐久性，已成为现代混凝土的基本组分。人们对于矿物掺合料的使用主要是基于碱或硫酸盐激发反应原理以利用其潜在胶凝性能，该理论多年来虽有所发展但未有新的实质突破，限制了矿物掺合料效能的充分发挥。项目拟从反应热动力学角度，深入研究矿物掺合料表面结构对其反应特性的影响规律，探明影响反应活性的关键参数与机理，建立不同矿物掺合料反应活性评价机制；研究矿物掺合料在不同温度/压力及水泥孔溶液环境驱动下离子溶出、迁移与沉积行为，揭示其与水化产物组成、结构之间关联性及影响机理；在此基础上，探索矿物掺合料水化热动力学行为的化学与物理调控方法，并提出矿物掺合料高效能应用技术以指导其科学应用，为其高效利用及混凝土高性能化发展提供理论与技术支撑。

Supplementary cementitious materials (SCMs) can significantly enhance the workability and durability of concrete, which have become a basic component of modern concrete. Usually, the use of SCMs is mainly based on the reaction theory of alkali or sulfate activation to utilize their potential binding performance. However, although this theory has been developed many years, it still doesn’t make a new breakthrough, which limits the full play of SCMs effectiveness. This project will study the intrinsic reactivity of SCMs with different surface characteristics, which caused by the mineral composition and thermal history. The key impact parameters and mechanism of intrinsic reactivity will be verified, and their evaluation methods also will be established. On the basis, the ions dissolution, migration and precipitation behaviors of SCMs in different curing temperature, pressure and pore solution conditions will be studied, which will build up the correlations between these behaviors and hydration products compositions and structures, and the corresponding reaction mechanism will also be ascertained. Furthermore, the physical and chemical adjusting methods of those behaviors will be proposed, and the high efficient application methods of SCMs will also be designed for their reasonable use in concrete. This research will provide the theoretical and technical supports for the efficient application of SCMs and the development of high performance concrete materials.