以Ni2P作为贵金属替代活性相，经一步转化过程，利用苯酚加氢脱氧原位生成的环己烯中间产物作为烷基化剂，实现木质素基苯酚类平台化合物的加氢自偶联，最终获得高碳数、高价值、低氢耗的C12芳烃产物连环己基苯。通过晶粒尺寸和形貌控制以及第二金属表面修饰实现Ni2P晶相表面Ni（I）及Ni（II）活性位的选择性暴露，从而调变表面上两种活性位的相对量, 以此实现对芳环加氢和酚羟基氢解两条反应路径的调控；运用新颖的磷化方法，调控表面B酸强度和密度，在Ni2P活性相磷化生成的过程中，同时产生B酸中心，实现金属活性位和B酸中心的均匀分布，改善二者的相互作用，缩短酸中心和金属活性位的空间距离，实现二者在原子尺度上的接近。以期达到对酸催化反应和加氢反应速率的精细调控。最终实现芳环加氢，酚羟基氢解，脱水反应，偶联反应的最佳耦合，使整个催化转化过程的各个反应路径达到最优化匹配。

Phenols are self-hydrocoupled and hydrodeoxygenated to C12 hydrocarbons in a tandem reaction over Ni2P surface using in-situ intermediate cyclohexene as alkylating agent. Using particle size and morphology control as well as a surface modification by Fe/Co ,the selective exposure of Ni（I）and Ni（II）active sites over Ni2P can be achieved, which adjusts the amount of the two types of active sites over the surface. So it can be realized to fine adjustment for the reaction rate between the hydrogenation and hydrogenlysis routes. The novel phosphorization method will be applied for the introduction of Bronsted acid sites simultaneously over the surface during the Ni2P synthesis in order to disperse Ni2P active phase and acid sites uniformly and improve the interaction between them to the closest. Thus the fine adjustment of reaction rate between hydrogenation and acid catalytic reaction can be expected. The reaction routes for the hydrogenation and hydrogenlysis catalyzed by Ni2P as well as solid acid-catalyzed dehydration and carbon–carbon coupling can be optimally balanced. It can be expected the highest yields to the aromatic product –cyclohexylbenzene from this single reaction sequence.