HCl的有效控制是实现城市生活垃圾（MSW）安全、洁净、可靠运行的必要条件。相对于烟气脱氯，燃烧脱氯技术有利于缓解受热面腐蚀，但脱除效率仍待提高。本项目采用多种实验表征法，辅助动力学、热化学平衡模拟计算，结合分子能量蓄积与键裂重组机理探寻O2/CO2燃烧对HCl生成的抑制机制，解析混烧时MSW组分间Cl-HCl转化的非线性耦合规律。基于燃烧介质和工况对煅烧、再碳酸化、直接/间接脱氯与烧结的促进/阻碍作用，揭示优化O2/CO2燃烧对HCl捕捉的促进机制；建立脱氯动力学模型，确定控速步骤；结合吸收剂表面与内部结构演化行为、活性成分催化作用及活性中心迁移特性，阐述复合调质提高脱氯性能的内在机理。基于燃烧方式创新、燃烧工况优化、脱氯剂调质的协同作用机理，形成垃圾燃烧脱氯的最优耦合策略。该研究工作旨在为减少MSW焚烧过程中HCl排放和腐蚀，开发和设计适用于MSW的O2/CO2燃烧锅炉提供理论支持。

The effective control of HCl is a necessary condition for the safe, clear and reliable operation in municipal solid waste (MSW) incineration power plants. Compared with flue gas dechlorination, the combustion dechlorination is better for alleviating the corrosion of heating surface, but its dechlorination efficiency need be further improved. By several experimental analytics, dynamic and thermochemical equilibrium simulation, combined with theoretics on the molecular energy accumulation and chemical bond break, the inhibiting mechanism of O2/CO2 atmosphere type on HCl formation is explored and the nonlinear coupling rule of Cl-HCl conversion among various MSW constituents during co-combustion is subjected. Based on the effects of combustion medium and condition on calcination, recanalization, direct/indirect dechlorination and sintering, the promoting mechanism of O2/CO2 combustion optimization on HCl control is explored. The dynamic model of dechlorination process is established, and the key step controlling the dechlorination rate is determined. Combined with the development of absorbers’ external and internal structure, catalysis of active constituent and migration feature of active center, the internal mechanisms of multiple modulated method on the improvement of dechlorination performance are clarified. Based on the mechanism of synergistic effect among the innovatory of combustion method, the optimization of combustion condition and the enhancement of dechlorination agents, the optimal coupling strategy on HCl combustion control for MSW is obtained. This research aims to provide useful information for alleviating the emission and corrosion behavior of acidic gases, and designing O2/CO2 combustion boilers applying in the solid waste treatment field.