有机固体废弃物生成途径及组分复杂，根据现实情况选择合适的处理处置技术尤为重要。本项目提出的基于熔融盐重整的有机固废电化学转化利用新思路，耦合热解、熔盐重整及直接碳燃料电池多系统，借助熔盐预处理促进热解挥发份中污染物脱除与组分重整，利用直接碳燃料电池将重整后挥发份的化学能转化为电能，实现有机固废的高效清洁利用。本项目的研究旨在揭示有机固废热解挥发份熔盐热处理过程中的重整特性，阐释熔盐环境下多污染物的脱除作用机理；探讨典型挥发份组分直接碳燃料电池中的热化学和电化学转化行为，明晰阳极熔融锡的添加对改善燃料电池电化学性能及抗结焦性能的作用机制。最终，基于熔盐重整及阳极熔融锡的添加提升有机固废挥发份直接碳燃料电池电化学转化的利用效率。本项目的实施将为有机固废的直接电化学转化提供理论依据，为城市固体废弃物的高效资源化利用开辟新的途径。

The formation route and composition of organic solid waste (OSW) are quite complicated. It is essential to select the appropriate treatment technology for the utilization of OSW according to the actual situation. The electrochemical conversion and utilization of OSW was proposed based on the molten salt pre-reforming. The efficient and clean reuse of OSW was realized by using direct carbon fuel cell (DCFC) systems coupled with pyrolysis and molten salt reforming treatment. In detail, the reforming of components in the pyrolysis volatiles as well as the removal of contaminants were performed by means of molten salt pretreatment. Then, the chemical energy of the reformed volatiles was converted into electrical energy by using a direct carbon fuel cell. . This project is launched to illuminate the reaction mechanisms between the molten salts and the volatiles from the pyrolysis of OSW. And the removal efficiency of contaminants in the high-temperature molten salts is to be further investigated. Meanwhile, the thermochemical and electrochemical behaviors of volatiles’ containing components will be estimated in DCFC. And the anode reactions in DCFC will be described with the addition of tin (Sn), and the key influence factors of the electrochemical performance will be clarified. At last, efficient and clean conversion methods of OSW pyrolysis volatiles in DCFC will be established by molten salts reforming and Sn addition in the anode. The successful implementation of this project will provide fundamental support for the electrochemical utilization of OSW in DCFC, and also help to develop a new way to the efficient and clean utilization of MSW.