生物质油酯加氢脱氧是发展高品质绿色洁净碳氢燃料的方向。针对催化油脂加氢脱氧中如何促进C-O键裂解抑制C-C键断裂实现同碳转化碳氢燃料的科学问题，采用溶剂蒸发诱导聚合组装调控双模板剂结构与改性载体表面策略，设计制备碳修饰掺杂亲氧性Zr/Zn短大孔硅基载体，适合长链油脂分子在孔内扩散避免C-C键碰撞断裂与堵塞；载体掺Zr增强B酸促进C-O键裂解又有利短大孔形成，碳修饰孔结构增强孔壁厚提高水热稳定性；超声湿法浸渍Ni-M(Co/Mo)分段焙烧，形成促进C-O裂解抑制C-C断裂的加氢脱氧活性位；调控Ni/M降低镍d带空穴提升H迁移率，抑制Ni对C=O羰基C的强吸附，促进C-O裂解；在催化剂构效关系与反应机理分析基础上，运用密度泛函理论与分子模拟计算，揭示催化油脂加氢脱氧同碳转化的反应机制，提供一种制备掺Zr短大孔硅基无硫非贵金属Ni-M催化剂催化油脂加氢脱氧同碳转化高品质绿色洁净碳氢燃料的新方法。

The same carbon conversion of biomass oil through hydrodeoxygenation is a direction for developing high quality green clean hydrocarbon fuel. It is a key scientific problem to promot C-O bonds cleavage and inhibit C-C bonds broken (usually including decarboxylation/carbonyl and long-chain alkane cleavage) in the hydrodeoxygenation of biomass oil converted to same hydrocarbon fuel. A strategy of the solvent evaporation induced polymerization assembly for adjusting double template agents structure and carrier surface modification is adopted. This project intends to do the following works: (1) Using a strategy of solvent evaporation induced polymerization assembly to control bi-template structure for design and synthesis of a Zr-doped with C and the oxyphilic Zr/Zn modified short-large-pore silica carriers, it is beneficial for reducing diffusion resistance and fracture of long-chain grease molecules into small molecular in carrier channels,where doping-Zr can enhance Brønsted acid sites to promote C-O bonds cleavage and facilitate the formation of short large pores to inhibite C-C bonds cleavage, and carbon-modifying pore structure can enhance wall thickness with both facilitating the loading of Ni-M bimetallic and improving the hydrothermal stability. (2) Using a method of ultrasonic wet impregnating Ni-M(Co/Mo) bimetallic followed by two-segmented calcination to remove the double-template agent, realize crystal transformation and to provide bimetallic active sites for hydrodeoxygenation, with the regulation of Ni/M to reduce nickel d band holes to increase the mobility of active hydrogen and bimetallic activites for inhibiting C=O bonds adsorption and promoting C-O bonds cleavage. (3) Based on the catalyst structure-activity and reaction mechanism analysis, combined with the DFT theoretical simulation, the reaction mechanism of the same carbon conversion of biomass oil to hydrocarbon fuel through hydrodeoxygenation over the Zr-doped short-large-pore silica Ni-M bimetallic catalysts will be disclosed, and a new method for preparing the Zr-doped short-large-pore silica sulfur-free Ni-M bimetallic catalysts and for the same-carbon converting of biomass oil to high quality green clean hydrocarbon fuel over will be developed.