柱芳烃具有特殊的结构和性能，是超分子化学的研究热点之一，但基于柱芳烃的聚合物荧光探针却未见报道。本项目利用柱芳烃特殊的主客体络合性能，设计合成结构新颖、荧光性质突出的柱芳烃聚合物荧光探针，建立其通用合成方法，并研究这种新型探针体系的基本科学问题（包括柱芳烃和聚合物结构与探针的主客体性能之间的关系，荧光基团和聚合物结构与探针的荧光性能之间的关系，探针的主客体性能和荧光变化之间的关系等），揭示其一般规律。本项目将拓展柱芳烃化学的研究领域，揭示荧光聚合物中超分子作用与荧光变化机制，开发荧光检测新材料并应用于环境污染物的检测，具有重要的理论意义和实际应用价值。

Chemistry of pillararene has developed rapidly as a new field of supramolecular chemistry. The core content of the chemistry of pillararene is to develop new functions of the host and to explore its application. This project focuses on the design and synthesis of novel fluorescent pillararene polymer probes (FP) with new functions, and applications in the new fields. By introducing a variety of chromophore groups and pillararene unit, a series of fluorescent pillararene polymer probes are prepared. The basic scientific topics of the fluorescent pillararene polymer probe system, such as the fluorescence performance, the host-guest properties, the selectivity for the threading of guest molecules in the macrocyclic cavities, the complexation and its selectivity, etc, will be studied, revealing the general scientific principles of the system. The fluorescent pillararene polymer probes will be applied to detect weak-polar organic molecules, such as haloalkanes. This design of fluorescent pillararene polymer probes might open up a promising fluorescent polymer probe with both host-guest property and fluorescent property for sensitve and selective detection of haloalkanes,anilines,quantenary ammonium, carboxylic acids,etc. This project has important significance for the development of pillararene chemistry and supramolecular science and applications in the environmental pollutant detection field.