CH4-CO2重整过程综合利用两种主要温室气体，实现C1资源循环利用。传统DRM过程强吸热、易积炭和反应难控制问题，是影响CH4-CO2重整技术在工业上应用的主要挑战。化学链技术可以将DRM过程强吸热的气-气反应解耦为两个连串步骤，不仅能有效提高目标产物的选择性，而且能有效降低反应温度。因而开展化学链技术提效的DRM重整反应新模式具有重要的学术意义和应用价值。本申请提出了构建低温“MoCx→MoCxOy”化学循环与传统“储氧体”化学复合新型储氧材料的设计思路，研制低温下活性、选择性、循环稳定性高的MoCx/Ni复合型CL-DRM催化剂，同时，借助原位XRD、红外（MS-DRIFS）、同位素示踪等表征手段，从分子水平上深入研究载氧体微观作用机制，揭示晶格氧迁移机理及调控本质，建立MoCx/Ni复合型载氧体的构效关系，以期为更高效CL-DRM催化剂的化学裁剪设计提供理论指导。

The dry reforming of methane reaction can comprehensively utilize the two major greenhouse gases of CH4&CO2 and realize the recycling of C1 resources. The traditional DRM process is characterized by strong heat absorption, easy carbon deposition and low reaction selectivity, which are the main challenges affection the industrial application of CH4-CO2 reforming technology. Chemical looping concept is opening an opportunity for the development of a new DRM reaction model to not only effectively improve the selectivity of the target product but also reduce the reaction temperature, because it permits the strongly endothermic gas-gas reaction of traditional DRM process to proceed separately as a cascade process of the Reduction and Oxidation reaction serially. And it is of great academic significance and application value for the new chemical looping DRM reaction model. Herein, we propose a strategy for the development of the MoCx/Ni composite catalyst with high activity, selectivity and cyclic stability at low temperature for the chemical looping DRM, by chemically fusing the “MoCx →MoCxOy” cycle that triggers the low-temperature methane partial oxidation by lattice oxygen atoms with the traditional oxygen storage carrier materials. The in-situ XRD, MS-DRIFS, isotope tracer method will be employed to explore the synergistic interaction between “MoCx → MoCxOy” cycle and the T-OSM. By doing so, we anticipate to in-depth study the microscopic action mechanism of the material from the molecular level, reveal the lattice oxygen transfer mechanism and regulation nature and build structure-activity relationship of the MoCx/Ni composite catalyst. We believe that our findings will stimulate the commercial exploitation of highly CL-DRM catalyst and such kind of methane conversion process.