锂离子电池的发展存在比能量低，安全性差等问题，开发锂离子电池新型电极材料是解决电池存在问题的有效途径。过渡金属氧化物 MO（M= Co, Ni, Cu, Fe, Cr）作为锂离子电池负极材料由于其比容量高，来源丰富，廉价易得等特点受到普遍关注。项目针对影响过渡金属氧化物电化学性能的表面性质和动力学性质进行了系统的分析与研究。该项目拟采用热氧化技术，制备不含导电剂和粘结剂的氧化物薄膜电极，用作锂电池负极材料。通过GIXRD、XPS、ToF-SIMS，AFM，SEM等分析表征手段对电极材料电化学前后的结构，形貌和光谱学性质进行表征，系统考察电解液和电极反应后的表面和界面性质，对反应后的电极材料进行结构分析，验证电极的转化储锂机理，并对该类材料的动力学性质运用电化学和光谱学两种方法进行评估，最后针对金属氧化物体积膨胀大，导电性差的特点，开发叠层生长制备金属氧化物/石墨烯复合材料薄膜电极的方法。

lithium-ion batteries suffer problems of low specific capacity and poor security. Development of novel electrode materials for lithium-ion batteries is an effective way to solve the problems. Transition metal oxides MO (M = Co, Ni, Cu, Fe, Cr), as the anode materials for lithium-ion batteries, have attracted attention due to its high specific capacity, environmental friendliness, abundance, and low cost. In this project, surface science and kinetic properties of the transition metal oxides were analyzed and studied. The project intends to adopt thermal oxidation method and epitaxial growth method to prepare thin film electrode without conductive additive and binder as anode for lithium-ion batteries. GIXRD, XPS, ToF-SIMS, AFM, SEM and other analysis tools are applied to characterize the structure, morphology and spectral properties of the electrode materials before and after electrochemical process. The surface and interfacial properties of electrode and electrolyte, the electrode structure after the electrochemical reaction, the mechanism of lithium storage are studied systematically, and the kinetic properties are evaluated by electrochemical and spectroscopic methods, respectively. Finally, to overcome the obstacles of large volume expansion and poor conductivity of transition metal oxides, laminated metal oxides/graphene composite thin film electrode is developed.