本项目针对水中新兴有机污染物（EOCs），拟采用可见光"增效"非均相芬顿过程，研究污染物的降解机制和催化剂失活机理。通过构筑具有可见光响应的"限域型"多孔碳/非均相芬顿催化剂，系统研究催化剂制备、光辅助"增效"非均相芬顿反应过程机理，旨在解决制约传统非均相芬顿催化过程的瓶颈问题。采用软硬模板法制备多孔碳基载体，设计合成以铁基过渡金属（水合）氧化物"限域"在多孔载体内，调控界面生长，形成在纳米尺度有效耦合的稳定复合结构。项目研究内容主要涵盖三部分：1）"限域型"多孔碳/非均相芬顿催化剂的设计、结构可控制备；2）优选出若干催化剂进行结构分析、界面电荷传递机理及催化反应过程表征；3）系统研究催化剂光辅助非均相芬顿降解EOCs的反应活性，双氧水催化分解动力学以及光辅助"增效"催化降解机制与催化剂失活机理。以上研究将为新型非均相芬顿催化剂的开发及其在高级氧化技术中的应用提供理论支持。

This project aims at the application of visible light-assisted heterogeneous Fenton process to study the degradation performance and mechanism of emerging organic contaminants (EOCs) in waterborne. We plan to construct a series of porous carbon/heterogeneous Fenton catalysts in which the metal (hydro)xides were confined within the porous networks and the obtained catalysts can adsorb and be activated by visible light. We plan to systematically study the preparing methods, visible light photo-assisted heterogeneous Fenton process. We plan to study the physical and chemical properties of the interface, the photo-generated charge transfer, and then solve the bottleneck problems that restricts the catalytic process of the traditional heterogeneous Fenton. The porous carbon carriers will be prepared by the hard/soft template strategy. The transition metal based (hydro)xides (such as iron compounds) are designed and confined in the porous carrier, and the interface is controlled to form a stable composite structure with effective coupling at the nanometer scale. The project mainly includes three parts: 1) design and controllable preparation of porous carbon/heterogeneous Fenton catalyst with "confinement effect "; 2) several selected porous carbon/heterogeneous Fenton catalysts for structural analysis, interfacial charge transfer mechanism and catalytic reaction process characterizations; 3) systematically studying the degradation efficiency of EOCs by visible light assisted heterogeneous Fenton process and the catalytic kinetics of hydrogen peroxide. The above basic research provides important research basis and theoretical guidance for the research and development of new heterogeneous Fenton catalyst and the utilization of solar energy in advanced oxidation technology.