创新性地设计、合成具有特定电子性质和立体结构的含氮、磷、硫等杂原子的单齿和多齿配体单体，采用Sonogashira偶联、Friedel-Crafts反应、自由基聚合、缩合反应等多种方法合成具有多级孔结构和高比表面积的有机多孔聚合物(POPs)，杂原子单齿和多齿配体单体既是过渡金属的配体也是聚合物的骨架，POPs杂原子单元结构的电子效应和立体效应，特别是POPs丰富的孔道结构和孔道的限域效应，将诱导或增强有机反应的区域选择性，研究POPs与Pd、Rh、Ru、Ni、Co、Fe等过渡金属配位，催化调控Heck反应、硅氢加成反应、加氢酰化反应、氢氨甲基化反应、Wacker氧化反应等几类区域选择性有机反应。在（a）区域选择性；（b）催化活性；（c）催化剂回收重复使用等三个方面开展创新性地系统研究，并深入研究这三者与POPs配体结构的关系，探索多相催化活性中心与区域选择性的关系及作用机理。

Innovatively design and synthesize N, P and S-doped mono- and multidentate monomers with a specific three-dimensional structure and electronic properties, through Sonogashira coupling, Friedel-Crafts, Suzuki coupling, free radical polymerization, condensation reactions and other methods for the synthesis of porous organic polymers with hierarchical pore structure and high specific surface area, the POPs are not only the ligands of transition metal but also solid polymer skeletons. The electronic and stereo effect of the hetero atom-doped POPs, especially the hierarchical pore structure and confinement effect, will induce or enhance the regioselectivity of organic reactions. The study of coordination of Pd, Rh, Ru, Ni, Co, Fe and other transition metals with POPs, catalytic regulation several selective organic reactions, such as Heck reaction, Hydrosilylation, Hydroacylation, Hydroaminomethylation, Wacker oxidation. Innovative and systematic research will be carried out in (a) regioselectivity; (b) catalytic activity; (c) catalyst reuse. In addition, we will study the relationship between the above three aspects and POPs ligand structure, explore the relationship between multiphase catalytic activity and regioselectivity as well as its mechanism.