Ni−Al−Co−Cr−B体系TLP连接的扩散动力学及金属间化合物溶解机理研究
结题报告
批准号:
51901203
项目类别:
青年科学基金项目
资助金额:
23.0 万元
负责人:
陈娟
依托单位:
学科分类:
E0101.金属材料设计、计算与表征
结题年份:
2022
批准年份:
2019
项目状态:
已结题
项目参与者:
--
国基评审专家1V1指导 中标率高出同行96.8%
结合最新热点,提供专业选题建议
深度指导申报书撰写,确保创新可行
指导项目中标800+,快速提高中标率
客服二维码
微信扫码咨询
中文摘要
镍基单晶高温合金焊接接头是制约航空发动机涡轮叶片服役性能和使用寿命的关键点,采用过渡液相(TLP)连接的镍基单晶高温合金接头处容易出现脆性金属间化合物残留的问题,严重影响高温合金的力学性能。揭示TLP连接固相均匀化过程中金属间化合物的溶解机制,有利于从根本上控制金属间化合物。因此,本项目拟选择Ni−Al−Co−Cr−B体系为研究对象,开展如下研究:(1)结合多元扩散节技术和数值回归方法高通量测定Ni−Al−Co−Cr−B合金的互扩散系数矩阵,进而获取该体系的原子移动性数据库;(2)基于热、动力学数据库,利用DICTRA软件模拟TLP连接固相均匀化过程中各元素的扩散路径和成分分布,阐明元素扩散机制;(3)研究固相均匀化阶段各类金属间化合物的溶解速率及影响因素,结合理论模拟和实验结果,揭示金属间化合物的溶解机理。本项目的完成将为镍基单晶高温合金TLP连接中间层合金设计和连接工艺的优化提供指导。
英文摘要
The welding joint of Ni-based single crystal superalloy is the key point to restrict the service performance and service life of aero-engine turbine blades. The brittle intermetallics are often observed in the joints bonded by transitional liquid phase (TLP), which seriously affects the mechanical properties of superalloys. The dissolution mechanism of intermetallics in the process of solid phase homogenization of TLP bonding should be revealed, which is beneficial to the fundamental control of intermetallic compounds. Therefore, this project will choose Ni-Al-Co-Cr-B system as the research object. The following studies will be carried out: (1) the diffusion coefficient matrix of Ni-Al-Co-Cr-B alloy will be measured in high throughput by combining the multi-element diffusion joint technique and numerical regression method, and then the atomic mobility database of the system will be obtained. (2) Based on thermal and kinetic database, the diffusion path and component distribution of each element in the process of solid phase homogenization of TLP bonding will be simulated by DICTRA software, and the diffusion mechanism of element will be clarified. (3) The dissolution rate and influencing factors of all kinds of intermetallics in solid phase homogenization will be studied. The dissolution mechanism of intermetallics will be revealed by theoretical simulation and experimental results. The completion of this project will provide guidance for the design of interlayer alloy of TLP bonding and the optimization of bonding process.
本项目针对镍基单晶高温合金接头处容易出现脆性金属间化合物残留而引起高温合金的力学性能下降的问题,提出选择Ni−Al−Co−Cr体系为研究对象,开展互扩散研究,并探索高熵合金作为镍基合金中间层的可行性。本项目重要研究成果如下:1)结合多元扩散节技术和数值回归方法高通量测定了γ和γ’相Ni−Al−Co−Cr合金的互扩散系数矩阵,并直接从成分距离曲线获取了该体系的原子移动性数据库,探讨了合金元素、温度、物相对于扩散系数的影响;2)选用Co-Cr-Fe-Ni高熵合金作为中间层合金,研究了其与Ni−Al−Co−Cr合金的相互扩散行为,Co-Cr-Fe-Ni高熵合金与γNi−Al−Co−Cr合金扩散后形成了固溶体,并且高熵加速了Al的扩散,减缓了Co的扩散;3)探索了Ni−Al−Co−Cr合金分别与低熵、中熵和高熵合金的扩散行为,揭示了熵、合金元素对互扩散系数的影响机制,阐明了元素的扩散机制。本研究将为镍基单晶高温合金焊接中间层合金的设计和连接工艺的优化提供理论和实践指导。
期刊论文列表
专著列表
科研奖励列表
会议论文列表
专利列表
Microstructure and wear behavior of FeCoNiCrMn high entropy alloy coating deposited by plasma spraying
等离子喷涂FeCoNiCrMn高熵合金涂层的显微组织与磨损行为
DOI:10.1016/j.surfcoat.2020.125430
发表时间:2020-03-15
期刊:SURFACE & COATINGS TECHNOLOGY
影响因子:5.4
作者:Xiao, Jin-Kun;Tan, Hong;Zhang, Chao
通讯作者:Zhang, Chao
Atomic mobilities and interdiffusivities in Ni-rich fcc Ni-Co-Cr and Ni-Al-Co-Cr systems evaluated using composition profiles and HitDIC
使用成分分布和 HitDIC 评估富镍面心立方 Ni-Co-Cr 和 Ni-Al-Co-Cr 系统中的原子迁移率和相互扩散率
DOI:10.1016/j.jallcom.2021.158645
发表时间:2021
期刊:Journal of Alloys and Compounds
影响因子:6.2
作者:Chen Juan;Xiao Jinkun;Lu Zhao;Wang Chengyin;Zhang Lijun
通讯作者:Zhang Lijun
DOI:10.1016/j.jallcom.2021.162711
发表时间:2021-11
期刊:Journal of Alloys and Compounds
影响因子:6.2
作者:Juan Chen;J. Xiao;Lijun Zhang
通讯作者:Juan Chen;J. Xiao;Lijun Zhang
Effect of carbon content on microstructure, hardness and wear resistance of CoCrFeMnNiCx high-entropy alloys
碳含量对CoCrFeMnNiCx高熵合金显微组织、硬度和耐磨性的影响
DOI:10.1016/j.jallcom.2020.156533
发表时间:2020
期刊:Journal of Alloys and Compounds
影响因子:6.2
作者:Jin-Kun Xiao;Hong Tan;Juan Chen;Ashlie Martini;Chao Zhang
通讯作者:Chao Zhang
Wear mechanism of Cu-based brake pad for high-speed train braking at speed of 380 km/h
时速380公里高速列车制动铜基刹车片磨损机理
DOI:10.1016/j.triboint.2020.106357
发表时间:2020-10-01
期刊:TRIBOLOGY INTERNATIONAL
影响因子:6.2
作者:Xiao, Jin-Kun;Xiao, Shu-Xian;Zhang, Chao
通讯作者:Zhang, Chao
国内基金
海外基金