今年化学学部发布了题为“团簇构造、功能及多级演化”的“重大研究计划2020年度项目指南”，将资助“团簇的功能与应用”的研究课题。在这份基金申请书中，我们提出“功能化异质团簇自组装成质子交换的多孔材料”的课题。我们将选择多酸团簇（POM+H+）和笼型倍半硅氧烷团簇（POSS）为原料，设计和合成含光可交联基团的POM+H+-OL-POSS异质团簇的两亲分子，然后自组装成具有双连续液晶立方结构的多孔材料。该材料内形成两套相互独立并三维贯通的质子（H+）纳米管道，可传导质子。光引发基团交联后形成交联聚合物，提高材料的力学性质。这样的材料能可作为质子交换膜用于燃料电池中，进一步拓宽多酸团簇应用范围，因此，研究内容是在“团簇的功能与应用”的范围内。

In 2020, the Department of Chemical Science released a major research program 2020 entitled "Cluster construction, Function and Multistage Evolution", which will fund the research project focused on "the function and application of clusters". Herein, we propose the project entitled "Self-Assembly of Functionalized Heteroclusters into Proton-exchangeable Porous Materials". We select polyacid clusters (POM+H+) and polyhedral oligomeric silsesquioxanes (POSS) to design and synthesize POM+H+-OL-POSS heteroclusters with photo-crosslinkable groups. They self-assemble into porous materials with bicontinuous liquid crystal cubic structures. The materials have two sets of the interpenetrating network of proton (H+) nanochannels. For this reason, such the materials can conduct protons. After the photo-crosslinkable group is photo-initiated to form a cross-linked polymer matrix, the mechanical properties of the materials are improved. The materials can be used as proton exchange membranes in fuel cells, so the application range of clusters is further expanded.