超分子形状记忆水凝胶可在外界刺激下通过可逆作用的形成或解离实现不依赖于热效应的形状记忆功能，是一种集感知、反馈、驱动为一体的智能高分子材料。与广泛研究的热致形状记忆高分子相比，目前对超分子形状记忆水凝胶的研究还较为滞后，亟需相应的材料设计与微观动态机制表征的新手段。本研究拟构筑可与稀土离子配位的高分子水凝胶，采用具有荧光发射能力的稀土配位作用固定材料的临时形状，从而发展出一种构建荧光超分子形状记忆水凝胶的新方法；系统研究形状记忆过程中材料荧光性能的精细调控规律，揭示荧光信号与形状记忆能力的关联机制，探索通过荧光信号从分子尺度表征形状记忆过程；进而利用材料形状回复过程的驱动行为及荧光性能的变化，实现复杂仿生驱动与智能变色的有机结合。本研究将丰富超分子形状记忆水凝胶的种类和构建方法，有助于深入理解其形状记忆机理，也为新型智能高分子材料的设计和开发提供实验和理论基础。

As one of the most important intelligent polymeric hydrogels including the functions of sensing, actuating and response, supramolecular shape memory hydrogels have the ability to “memorize” a temporary shape, and recover to the original shape through the combination and dissociation of molecular switches via external stimuli. Compared with the studies of classic thermo-induced shape memory polymers, the researches of supramolecular shape memory hydrogels are highly lagging, it is urgent need to explore new method to fabricate supramolecular shape memory hydrogels, as well as investigate the dynamic process of shape memory performance. This project is proposed to fabricate novel polymeric hydrogels that are able to complex with lanthanide ions, the lanthanide-ligand coordination with fluorescence-emitting behavior will be applied to stabilize temporary shapes, supramolecular shape memory hydrogels with fluorescence-emitting behavior will be obtained. The relationship between the fluorescence properties and shape memory effects will be investigated, and a new approach for investigating the process and dynamics of coordination-triggered supramolecular shape memory will be explored by employing the fluorescence method. Taking the advantage of the actuating process during shape recovery, biomimetic hydrogel actuators with simultaneously shape deformation and fluorescence color-changing functions will be developed. This research will enrich the design strategy of supramolecular shape memory hydrogels, promote the understanding of the dynamic metal-coordination supramolecular shape memory process, and inspire the design and fabrication of novel intelligent polymeric materials.