含三嗪单元的共价键连缺电子分子容器

分子容器的设计合成与应用研究是超分子化学的重要研究内容，本项目基于协同作用的理念、以缺电子芳环为基本单元、采取多样性导向合成策略、设计并合成具有复杂拓扑结构的缺电子分子容器，研究阴离子介导的具有编辑特点的分子容器-分子容器的转换、分子容器对特定几何形状的无机阴离子和复杂有机阴离子的选择性识别以及探索分子容器对化学反应过程的调控。

Design and synthesis of molecular container is a central topic in supramolecular chemistry. Based on the principles of cooperative interactions, this project aims to set up a diversity-oriented synthetic protocol to construct electron-deficient molecular containers with complicated topological structures. The anion-mediated molecular edit of container-container transformation, selective anion recognition towards inorganic anions of specific geometry and complicated organic anions, and molecular container regulated organic reactions will then be systematically studied.