课题基金 / 基金详情

新型非晶碳基薄膜压阻材料与MEMS器件关键技术

批准号:
U20A20296
项目类别:
联合基金项目
资助金额:
260.0 万元
负责人:
汪爱英
学科分类:
微纳及原子级制造
结题年份:
2024
批准年份:
2020
项目状态:
已结题
项目参与者:
汪爱英

项目摘要

结项摘要

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中文摘要
传统硅基MEMS传感器制造工艺简单,线性度好,但压阻系数低、基体适用窄,应用受限。非晶碳基薄膜机械防护性能优异、压阻系数大、低温大面积制备能和MEMS技术兼容,作为新型碳基压阻材料,备受关注。然而因碳基薄膜体系多样、键态表征复杂,有关压阻机理不明。本项目基于材料设计制备与器件结构优化的研究思路,重点选择无氢a-C、含氢a-C:H、金属掺杂a-C:Me的三类碳基薄膜为对象,聚焦非晶碳基薄膜压阻材料与MEMS传感器关键技术展开研究,旨在建立复合PVD非晶碳基薄膜材料的设计制备方法,结合微结构演变揭示压阻机理,通过敏感结构、电路电极、加工技术等仿真优化,明确非晶碳膜MEMS压阻器件的设计理论和工作原理,结合膜基表/界面匹配控制,发展兼具高灵敏度、微型化、批量稳定的高性能非晶碳基薄膜MEMS器件关键技术,相关结果不仅助于深入理解碳基压阻材料基础理论,且为发展空天、海洋用新一代传感器奠定重要基础。
英文摘要
With the development of aerospace, ocean, intelligent manufacturing and other high-tech industries, traditional silicon-based piezoresistive sensors can not meet the performance requirements under some harsh environments. Due to their excellent protective property, high piezoresistive sensitivity and good compatibility with silicon-based MEMS technology, study on amorphous carbon based piezoresistive materials and MEMS devices has become a hot spot, both at home and abroad, which can also promote the MEMS industry of Zhejiang Province. Till now, the piezoresistive mechanism of amorphous carbon based films is unclear, and integration of amorphous carbon based MEMS device still face many technical challenges. In this project, according to the different bonding characteristics between metallic atom with carbon, hydrogen-free, hydrogen-containing, and Ti (bonding), Cr (non-bonding), Cu (anti-bonding), Al (ion-bonding) doped amorphous carbon films were selected, by systematically investigating their microstructure and piezoresistive behaviors, related piezoresistive mechanism can be clarified. In addition, the design, processing, packaging and power supply of the amorphous carbon based MEMS device will be systematically investigated, and the integration technology of amorphous carbon based MEMS device can be obtained, the application of the amorphous carbon based MEMS device will be carried out under harsh conditions such as sea water, high and low temperatures. This project will help to understand the basic theory of amorphous carbon based films, and promote their application in intelligent manufacturing, aerospace, marine and other fields.
该项目针对目前高性能MEMS传感器存在微纳设计制造困难、压阻性能受限、严苛环境耐久性差等关键挑战,聚焦新型非晶碳基薄膜压阻材料的设计制备、压阻效应、MEMS器件加工、服役性能评测方面开展了研究,取得主要创新成果包括:1)材料体系特色:对比研究了四大类无氢非晶碳(a-C)、含氢非晶碳(a-C:H),Cu、Ti、Al、Cr四种成键特征金属掺杂碳膜材料体系的设计制备、结构表征及压阻行为规律;发展了含Cu、Al金属微纳结构的非晶碳基薄膜压阻材料新体系,相比纯碳基薄膜体系GF提升4倍以上。2)基础理论创新:建立了系列碳基薄膜的压阻机理模型,提出sp2相团簇初始间距决定了纯碳膜隧穿几率变化幅度,即压阻系数GF大小;结合原位Raman、导电原子力显微镜(C-AFM)及理论计算,阐明了应力动态过程中,sp2团簇含量/大小及异质导电相分布是决定非晶碳材料压阻性能的核心本质。3)器件集成技术:研发了平膜、悬臂梁等敏感结构非晶碳MEMS器件,建立了a-C/Si3N4/SiO2微压传感器及高效低成本流片工艺;明确了非晶碳MEMS传感器封装方案,完成了仿真验证与基础测试;发展出新型非晶碳柔性传感器,实现灵敏度GF及大范围测试,可实现手腕脉搏,手指弯曲,膝盖弯曲,肘部弯曲等可靠检测。相关研究成果可为智能制造、航空航天、海洋装备等领域高性能传感器提供材料设计、结构原理、工艺集成的理论依据和技术指导。.通过项目实施,发表学术论文24篇(SCI 23篇),申请国家发明专利16件(授权4件),培养科技创新青年人才18人,其中引进及出站博士后4名,晋升高级职称3人,培养硕士和博士研究生11人(1人获浙江省优秀毕业生)。牵头制定碳基薄膜命名与分类国家标准1项,获得第二届宁波市高价值专利大赛发明金奖、陕西省技术发明一等奖、中国腐蚀与防护学会科学技术一等奖各1项,科研骨干和研究生获各类奖项30余人次。
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