多级g-C3N4/Carbon复合物的合成及可见光光催化研究
结题报告
批准号:
51402147
项目类别:
青年科学基金项目
资助金额:
25.0 万元
负责人:
张林飞
依托单位:
学科分类:
E0205.无机非金属基复合材料
结题年份:
2017
批准年份:
2014
项目状态:
已结题
项目参与者:
程春、林谋宏、徐仁霞
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中文摘要
碳材料和碳氮材料被认为是一种有望广泛应用于污染控制领域的新型非金属材料。他们具有比表面积大,吸附能力强的优点,常作为金属催化材料的载体使用,起到增加对目标物的吸附,促进催化反应发生的作用。金属材料价格相对昂贵、在反应过程中容易溶出而危害环境。如果能够用非金属,例如碳材料和碳氮材料,完全替代金属,实现对目标反应的高效催化,将有效降低污染物控制过程的成本并提高处理过程的环境安全性。因此,本项目拟借助多功能复合材料的优势,拟通过构建以多级结构的g-C3N4/C复合材料为主的少用甚至不用金属的新型复合催化剂,借助复合掺杂等手段,来提高污染物的催化降解效率和催化降解成本,有效的促进其在光催化领域和热催化领域的应用。这将有助于开发高效低成本环境友好型碳材料及碳氮材料的工业催化剂,促进其在污染控制领域的应用。
英文摘要
Carbon and carbonitride materials are considered as novel types of non-metallic materials which can be widely used in the field of pollution control. Owing to their remarkable large surface area and strong adsorption capacity, carbon and carbonitride materials are widely used as substrates for metal catalytic materials, served for increasing the adsorption of target reactants and promoting catalytic reaction. Metal materials are relatively expensive, and easily dissolved in the reaction process, resulting in harming the environment. If we can use non-metallic, such as carbon and carbonitride materials to replace metal materials completely, will expect to achieve catalytic reaction and reduce the cost of pollution control process efficienlly as well as improve the environmental security of the process. Therefore, this project intends to take advantage of the multifunctional composite materials, building with hierarchical structured carbonitride/carbon (g-C3N4/C) composite catalytic materials, which were mainly composited of carbon and carbonitride materials with less or without noble metal phase. By means of compositing and doping, the improved efficiency and reduced cost of visible light degradation of pollutants were achieved.achieved improved applications in the field of photocatalysis and thermocatalysis. These results are expected to develop efficient, low-cost and environment-friendly carbon and carbonitride catalytic materials, as well as to promote their applications in the field of pollution control.
本课题通过直接煅烧热回流处理过的乙烯基二膦酸-三聚氰胺复合物的方法,合成了一种富含介孔和微孔的石墨相氮化碳(g-C3N4)微米棒。这种磷掺杂石墨相氮化碳微棒(P-CNRs)表现出很高的催化活性:它光解水制氢的效率高达4960μmolh-1g-1(是普通g-C3N4的5.5倍),并且有非常高的循环稳定性。它的优异性能来自于P-CNRs经过精心设计的结构和良好的电学性能。其层级结构有助于光子的散射,并提供了很大的比表面积,从而增加有催化性的活性位点数目。磷的掺杂缩小了催化剂的带隙,从而极大地增加了催化剂对可见光的吸收,它同时也增加了催化剂导带的态密度。P-CNRs的光制发光谱展现出其具有很强的可见光发射淬灭,说明电荷转移得到了增强。同时课题也作了光催化制氢与电催化制氢的比较以及电化学储能材料的合成与储能器件的制作工艺研究。在课题后期拓展了研究方向,以ZnO纳米棒阵列为研究对象,开始染料敏化太阳能电池的初期探索。项目资助发表核心论文7篇。培养科研型本科生1名。项目投入经费25万元,支出22.3625万元,各项支出基本与预算相符。剩余经费2.6375万元。剩余经费计划用于本项目研究后续支出。
期刊论文列表
专著列表
科研奖励列表
会议论文列表
专利列表
V(2)O(5)-C-SnO(2) Hybrid Nanobelts as High Performance Anodes for Lithium-ion Batteries.
V2O5-C-SnO2 混合纳米带作为锂离子电池的高性能负极
DOI:10.1038/srep33597
发表时间:2016-09-28
期刊:Scientific reports
影响因子:4.6
作者:Zhang L;Yang M;Zhang S;Wu Z;Amini A;Zhang Y;Wang D;Bao S;Lu Z;Wang N;Cheng C
通讯作者:Cheng C
DOI:10.1016/j.mtener.2017.05.006
发表时间:2017-09
期刊:Materials Today Energy
影响因子:9.3
作者:Linfei Zhang;Yi Zhang;R. Shi;Shuhan Bao;Jingwei Wang;Abbas Amini;B. Chandrashekar;Chun Cheng
通讯作者:Linfei Zhang;Yi Zhang;R. Shi;Shuhan Bao;Jingwei Wang;Abbas Amini;B. Chandrashekar;Chun Cheng
DOI:10.1038/srep18886
发表时间:2016-01
期刊:Scientific Reports
影响因子:4.6
作者:Run Shi;Chengzi Huang;Linfei Zhang;Abbas Amini;Kai Liu;Yuan Shi;Shuhan Bao;Ning Wang;Chun Cheng
通讯作者:Chun Cheng
A Laser Irradiation Synthesis of Strongly-coupled VOx-reduced Graphene Oxide Composites as Enhanced Performance Supercapacitor Electrodes
激光辐照合成强耦合 VOx 还原氧化石墨烯复合材料作为增强性能超级电容器电极
DOI:10.1016/j.mtener.2017.07.004
发表时间:2017
期刊:Materials Today Energy
影响因子:9.3
作者:Zhang LinFei;Jun Tang;ShiYuan Liu;OuWen Peng;Run Shi;B. N. Ch;ru;Yan Li;Xin Li;XiangNan Li;BaoMin Xu;Chun Cheng
通讯作者:Chun Cheng
Y-shaped ZnO Nanobelts Driven from Twinned Dislocations.
由孪生位错驱动的 Y 形 ZnO 纳米带
DOI:10.1038/srep22494
发表时间:2016-03-02
期刊:Scientific reports
影响因子:4.6
作者:Shi Y;Bao S;Shi R;Huang C;Amini A;Wu Z;Zhang L;Wang N;Cheng C
通讯作者:Cheng C
国内基金
海外基金