采用本课题组发展的新方法制备NiSiO、NiAlO、NiZrO、NiZrAlO、NiCoSiO、NiMoAlO等高表面积复合氧化物介孔材料，将它们还原、硫化或者磷化，生成介孔载体担载的高分散纳米金属、合金、金属硫化物和金属磷化物等催化剂。其中高活性纳米金属镍催化剂具有很高的活性表面积（50-100 m2/g-催化剂），可用于邻苯二甲酸二异癸酯（DIDP）和双酚A（BPA）等较大分子中的苯环加氢反应。而高分散的金属硫化物具有较强的表面酸性和加氢活性，可同时用于烯烃骨架异构和噻吩加氢脱硫（汽油）。而高分散的金属磷化物催化剂则可用于二苯并噻吩加氢脱硫和四氢萘加氢饱和（柴油），还可用于含硫气氛中的双键加氢饱和，例如蒎烯加氢和C5石油树脂加氢，此外，还可以尝试将其用于含硫气氛中C9石油树脂的苯环加氢饱和反应，这种抗硫中毒的高活性加氢催化剂在化学工业中具有重要的应用价值。

High surface area and mesoporous complex oxides such as NiSiO, NiAlO, NiZrO, NiZrAlO, NiCoSiO and NiMoAlO will be prepared by a new method developed by our group. Reduction, sulfidation and/or phosphatization of these complex oxides lead to the formation of highly dispersed metals, alloys, metal sulfides and metal phosphides on mesoporous suppports. The highly active nano nickel catalysts may have the high active surface areas of nickel (50-100 m2/g) and may be used for the the hydrogenation of aromatic rings in some large molecules such as di-isodecyl (o-)phthalate (DIDP) and bisphenol A (BPA). The highly dispersed metal sulfides may exhibit strong surface acidity and hydrogenation activity and thus may be used for the hydrodesulfurization of thiophene and skeletal isomerization of olefins simultaneously (for gasoline). The highly dispersed metal phosphides will be used for the hydrodesulfurization of di-benzyl thiophene and hydrogenation of tetralin (for diesel). The active metal phosphides will also be used for the hydrogenation of C=C double bonds in pinene and C5 petroleum resins that may contain some organic sulfurs. They can even be used for the hydrogenation of aromatic rings in C9 petroleum resins containing organic sulfurs. Such hydrogenation catalysts resistant to sulfurs are of great importance in chemical industry.