线性四氮配体金属-双氧配合物合成、表征及反应活性研究

本项目针对目前仿生催化氧化、氧分子活化中亟待解决的问题，合成基于各种sp2氮杂环及二胺骨架的线性（手性）N4配体及其金属配合物，并利用这些配合物获得相应的金属-O2配合物，开展相应的谱学、结构表征，并获得不同种类线性N4配体金属-O2配合物结构、物理化学性质等，为温和条件下氧分子活化及利用提供理论和实验依据。在仿生催化领域形成自己的特色的研究工作。

Toward the pivotal problems in the field of catalytic oxidation and dioxygen activation,a series of tetradentate nitrogen ligands derived from various diamines and heterocycle with different sp2 nitrogen together with their metal complexes will be designed and synthesized. To get direct evidence for the understanding the key intermediates involved in dioxygen activation chemistry, the synthesis, structural and spectroscopic characterization, and reactivity of metal-O2 complexes bearing linear tetradentate nitrogen ligands will be performed.