Solar-driven all-in-one MOFs-based catalyst for highly efficient CO2 conversion
Solar-driven all-in-one MOFs-based catalyst for highly efficient CO2 conversion
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太阳能驱动的一体化 MOF 催化剂可实现高效二氧化碳转化
DOI：
10.1016/j.apcatb.2022.121878
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发表时间：
2022-08
期刊：
影响因子：
--
通讯作者：
Xinsheng Peng
中科院分区：
文献类型：
--
作者：
Zhou Fang;Rongren;Yuqi Wang;Yue Hu;Mengyang Dong;Zhezhen Ye;Qinggang He;Xinsheng Peng
CO2fixation and conversion are desirable to solve the exceeding CO2emission. Traditional CO2cycloaddition needs strict conditions, co-catalyst and solvent, causing energy intensive and complex recycle process. In this work, an integrated ionic polymers (IPs) and phosphomolybdate (PMo12) co-modified CuTCPPCo MOF all-in-one composite catalyst (PBPCT*) is designed for solar driven, solvent-free and co-catalyst-free CO2cycloaddition. The PMo12clusters and IPs offer abundant active sites for reactants activation and ring opening. The activation energy significantly decreases from 66.36 kJ·mol-1of CuTCPPCo MOF to 49.47 kJ·mol-1of PBPCT*, and guarantees higher efficient with 99.2% yield of styrene carbonate at 353 K for 12 h. The TOF of 580.73 h-1under light density of 0.8 W/cm2superior to traditional heating with TOF of 473.0 h-1. This provides a new avenue to gather all the advantages in one catalyst, furnishing a promising approach for reducing CO2emission and utilization.
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影响因子：
3.8
作者：
Jia-zheng Lu;Jin-wang Huang;Li-Fen Fan;Jie Liu;Xianli Chen;L. Ji
通讯作者：
Jia-zheng Lu;Jin-wang Huang;Li-Fen Fan;Jie Liu;Xianli Chen;L. Ji
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影响因子：
29.4
作者：
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通讯作者：
Li Can
影响因子：
4.6
作者：
Satyabrata Subudhi;Sriram Mansingh;G. Swain;Arjun Behera;Dharitri Rath;K. Parida
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影响因子：
15
作者：
Li, Pei-Zhou;Wang, Xiao-Jun;Zhao, Yanli
通讯作者：
Zhao, Yanli
影响因子：
3.3
作者：
Anand, Resmi;Borghi, Francesco;Monti, Sandra
通讯作者：
Monti, Sandra