Highly regioselective synthesis of chiral diamines via a Buchwald–Hartwig amination from camphoric acid and their application in the Henry reaction
Highly regioselective synthesis of chiral diamines via a Buchwald–Hartwig amination from camphoric acid and their application in the Henry reaction
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樟脑酸 BuchwaldâHartwig 胺化高度区域选择性合成手性二胺及其在 Henry 反应中的应用
DOI：
10.1002/aoc.3162
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发表时间：
2014
影响因子：
3.9
通讯作者：
R. Wilhelm
中科院分区：
文献类型：
--
作者：
M. Uzarewicz-Baig;M. Koppenwallner;S. Tabassum;R. Wilhelm
本文介绍了以樟脑酸为原料合成新型不对称二胺配体的方法。新的二胺可以高产率地以(+)-顺-1，2，2-三甲基环戊烷-1，3-二胺中受阻较小的伯胺基团的形式直接制备。得到的二胺含有仲胺和伯胺基团，并成功地作为配体应用于铜催化的反应中。版权所有©2014 John Wiley&Sons，Ltd.
In this work the synthesis of new asymmetric diamine ligands from camphoric acid is described. The new diamines can be directly prepared in a of the less hindered primary amine group of (+)-cis-1, 2, 2-trimethylcyclopentane-1, 3-diamine via a in high yields. The resulting diamines incorporate a secondary and primary amine group and were successfully applied as ligands in a copper-catalyzed. Copyright© 2014 John Wiley & Sons, Ltd.
影响因子：
--
作者：
Boruwa, Joshodeep;Gogoi, Naminita;Barua, Nabin C.
通讯作者：
Barua, Nabin C.
影响因子：
16.6
作者：
Palomo, C;Oiarbide, M;Mielgo, A
通讯作者：
Mielgo, A