Mafic-hosted seafloor sulfide mineralization at the margin of a non-transform discontinuity on the southern mid-Atlantic ridge

Mafic-hosted seafloor sulfide mineralization at the margin of a non-transform discontinuity on the southern mid-Atlantic ridge
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大西洋中脊南部非转换间断边缘的镁铁质海底硫化物矿化

DOI:
10.1080/1064119x.2018.1485066
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发表时间:
2018-07
影响因子:
2.2
通讯作者:
Li Bing
Li Bing
中科院分区:
工程技术3区
文献类型:
--
作者:
Li Bing

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摘要对位于南大西洋中脊(SMAR)非转换不连续面(NTD)边缘的太极田(包括太极1和太极2)海底块状硫化物(SMS)和热液蚀变岩进行了矿物学、地球化学和硫同位素研究。太极1号热液沉淀物主要为块状硫化物,太极2号热液沉淀物主要为半块状硫化物。岩石蚀变明显,半块状硫化物中含有大量粘土矿物。在地球化学上,成岩元素(Mg)与半硫化物中的主要热液金属元素(Zn + Cu和Co)之间存在显著的负相关关系。这些矿物学和地球化学特征,以及半块状硫化物的低Co/Ni比值(与围岩相似)和某些蚀变岩的独特稀土元素特征,表明这些半块状硫化物的主要成矿机制可能与岩石成矿作用有关。因此,太极2号与太极1号在硫化物成矿机制上存在显著差异。此外,太吉硫化物的δ ~(34)S变化幅度较大(7.2-15.3%)。我们认为硫化物沉淀后的海水腐蚀是硫化物中34 S富集的原因。此外,我们的工作提供了一些线索,在太极和其他NTD相关领域之间的比较沿着大西洋中脊。我们认为,岩石矿化可能是一个重要的矿化类型NTDs。
Abstract Mineralogical, geochemical and S-isotopic studies were carried out on seafloor massive sulfides (SMS) and hydrothermally altered rocks from the mafic-hosted TaiJi field (including TaiJi-1 and TaiJi-2 sites), which is located on the margin of a nontransform discontinuity (NTD) on the Southern Mid-Atlantic Ridge (SMAR). The main hydrothermal precipitates of TaiJi-1 were massive sulfides, while TaiJi-2 produced a large amount of semi-massive sulfides. Significant rock alteration is an important feature of this field, and large amounts of clay minerals (chlorite) occurred in the semi-massive sulfides. Geochemically, notable negative correlations were identified between rock forming elements (Mg) and major hydrothermal metal elements such as Zn + Cu and Co in semisulfides. Such mineralogical and geochemical characteristics, together with low Co/Ni ratio (similar to the surrounding rocks) of the semi-massive sulfides and the unique REE features of some altered rocks, tell us that the prominent mineralization mechanism for these semi-massive sulfides was probably related to rock mineralization. Thus, TaiJi-2 appears to differ significantly from the TaiJi-1 in terms of sulfide mineralization mechanism. Moreover, the TaiJi sulfides are remarkable for large δ34S variation (7.2–15.3%). We suggest that seawater corrosion after sulfides precipitation were responsible for 34S enrichment in sulfides. Furthermore, our work sheds some light on the comparison between TaiJi and other NTD-related fields along the Mid-Atlantic Ridge. We argue that rock mineralization may represent an important mineralization type in NTDs.
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