Ion exchanged YVO4:Eu3+ nanocrystals and their strong luminescence enhanced by energy transfer of thenoyltrifluoroacetone ligands

Ion exchanged YVO4:Eu3+ nanocrystals and their strong luminescence enhanced by energy transfer of thenoyltrifluoroacetone ligands
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离子交换的 YVO4:Eu3 纳米晶体及其通过噻吩酰三氟丙酮配体的能量转移增强的强发光

DOI:
10.1016/j.jallcom.2013.12.112
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发表时间:
2014-03
影响因子:
6.2
通讯作者:
Du Guoping
Du Guoping
中科院分区:
材料科学2区
文献类型:
--
作者:
Tang Lu;Gui Weijun;Ding Kanjunjie;Chen Nan;Du Guoping

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In this work, undoped YVO4nanocrystals (10–15 nm in size) were first synthesized by a solvothermal method, and they were ion exchanged for Eu3+ions to form YVO4:Eu3+nanocrystals, which were then used to prepare YVO4:Eu3+–thenoyltrifluoroacetone hybrid nanostructures. As expected, the ion exchanged YVO4:Eu3+nanocrystals exhibited the characteristic V–O charge transfer excitation band. Much stronger luminescence has been observed in the YVO4:Eu3+–thenoyltrifluoroacetone hybrid nanostructures due to energy transfer from thenoyltrifluoroacetone ligands to Eu3+ions. The dependence of luminescence of the YVO4:Eu3+–thenoyltrifluoroacetone hybrid nanostructures on the Eu3+concentration and amount of thenoyltrifluoroacetone ligands was investigated in detail, and optimal preparation conditions were determined. Their UV–Vis absorption spectra and BET specific surface area were measured. X-ray diffraction technique, transmission electron microscopy, and Fourier transform infrared spectroscopy were used to study their microstructural characteristics.
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