Photo-induced magnetic properties of the [CuII(bapa)]2[MoIV(CN)8]·7H2O molecular ribbon
Photo-induced magnetic properties of the [CuII(bapa)]2[MoIV(CN)8]·7H2O molecular ribbon
复制标题
[CuII(bapa)]2[MoIV(CN)8]·7H2O分子带的光致磁性能
DOI：
10.1039/c5tc01889g
复制
发表时间：
2015
影响因子：
6.4
通讯作者：
B. Sieklucka
中科院分区：
文献类型：
--
作者：
O. Stefańczyk;A. Majcher;M. Rams;W. Nitek;C. Mathonière;B. Sieklucka
A unique one-dimensional ribbon [Cu(bapa)]2[Mo(CN)8]·7H2O (1) (bapa = bis(3-aminopropyl)amine), consisting of {[Cu(bapa)]3[Mo(CN)8]2}2− trigonal bipyramids and {[Cu(bapa)]2[Mo(CN)8]2}4− rhombuses linked through [Cu(bapa)]2+, was obtained and its photomagnetic properties were investigated. After irradiation at selected wavelengths (405 and 532 nm) or with white light, a global increase of the magnetic moment was observed. The initial state of the compound can be fully recovered by heating the sample above the temperature of relaxation of 253 K. This work was completed with photoreversibility studies with red and IR light irradiation which confirm a partial light-induced reversibility of the photomagnetic effect in 1. Finally, the photomagnetic phenomenon in 1 is discussed in accordance with two processes: the spin crossover on Mo(IV) centres and the metal-to-metal charge transfer mechanism in the Cu(II)–Mo(IV) pair.
登录
查看更多内容
影响因子：
15
作者：
T. Hozumi;K. Hashimoto;S. Ohkoshi
通讯作者：
T. Hozumi;K. Hashimoto;S. Ohkoshi
影响因子：
3.1
作者：
Wen Zhang;Haoling Sun;O. Sato
通讯作者：
Wen Zhang;Haoling Sun;O. Sato
影响因子：
15
作者：
Nihei, Masayuki;Sekine, Yoshihiro;Oshio, Hiroki
通讯作者：
Oshio, Hiroki
电化学合成分子磁体的非线性磁光效应和光磁性
DOI：
--
发表时间：
2007
期刊：
J.Solid State Electrochem 11
影响因子：
--
作者：
豊田 真智子;山口 実靖;小口 正人;Hiroko Tokoro;Hiroko Tokoro;Yusuke Konishi;Shin-ichi Ohkoshi;Shunsuke Sakurai;Tomohiro Nuida
通讯作者：
Tomohiro Nuida