Chiral Organic Dyes Endowed with Circularly Polarized Laser Emission.

Chiral Organic Dyes Endowed with Circularly Polarized Laser Emission.
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DOI:
10.1021/acs.jpcc.7b00654
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发表时间:
2017-03-09
期刊:
The journal of physical chemistry. C, Nanomaterials and interfaces
影响因子:
--
通讯作者:
de la Moya S
de la Moya S
中科院分区:
其他
文献类型:
--
作者:
Jiménez J;Cerdán L;Moreno F;Maroto BL;García-Moreno I;Lunkley JL;Muller G;de la Moya S

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直接产生高效、可调谐、可切换的圆偏振激光在光子学和材料科学中具有深远的意义。在本文中,我们描述了第一个手性简单有机分子(SOMs)能够同时保持显著的化学稳健性,高荧光量子产率和圆极化发光(CPL)椭圆度水平(|glum|)与类似的cpls -SOMs相当。所有这些参数共同实现了高效的激光发射和比本征CPL强2个数量级的椭圆能级CPLE。
The direct generation of efficient, tunable, and switchable circularly polarized laser emission (CPLE) would have far-reaching implications in photonics and material sciences. In this paper, we describe the first chiral simple organic molecules (SOMs) capable of simultaneously sustaining significant chemical robustness, high fluorescence quantum yields, and circularly polarized luminescence (CPL) ellipticity levels (|glum|) comparable to those of similar CPL-SOMs. All these parameters altogether enable efficient laser emission and CPLE with ellipticity levels 2 orders of magnitude stronger than the intrinsic CPL ones.
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