Amphiphilic Association Structures of Prepolymerized Compounds (Expedited Award; Industry/University Cooperation)

本项目是对两亲性聚合物领域研究的一个介绍 协会的结构和处理专门与最近发现的 （胶束）两亲聚合物结构。 预期结构 联合收割机将正胶束和反胶束的微区室化 具有聚合体系的高稳定性。 这些新的结构 为类似于酶的新催化体系提供了潜力， 用于从催化水中分离产物的新膜系统 裂解反应和用于聚合体系的引发剂。 该项目中组合结构的基础是六烷基 (1st星型聚乙烯亚胺三季铵盐 碘化物（HAAI），一种将使用已知的方法合成的化合物， 六甲基（第一代）星状聚乙烯亚胺的方法。 化合物HAAI本身是聚合的反胶束，并且其 溶剂化能力及其对酯催化作用 水解是基本信息。

This project is an introduction to research in the area on amphiphilic association structures and deals specifically with a recent discovered (micellar) amphiphilic polymer structure. The expected structures combine the micro-compartmentalization of normal and inverse micelles with the high stability of polymerized systems. These new structures provide a potential for new catalytic systems similar to enzymes, for new membrane systems for separation of products from catalytic water splitting reactions, and for initiators for polymerization systems. The basis for combination structures in this project is the hexalkyl (1st generation) starburst polyethyleneimine tris quarternary ammonium iodide (HAAI), a compound which will be synthesized using the known methods for hexamethyl (1st generation) starburst polyethyleneimine. The compound HAAI is, per se, a polymerized inverse micelle and its solutilization capacity as well as its catalytic action on ester hydrolysis are essential information.