Development of Multipolar Zero-Field NMR Spectroscopy ethods

该奖项是Chmelka博士的启动补助金增量 化学博士后奖学金。这项工作将发展 多极零场核磁共振方法学 改进.将减少样本穿梭时间， 使研究自旋晶格较短的系统成为可能 放松时间可达偶极耦合的范围 将扩展到50 kHz，以便固体有机化合物可以 被研究。新仪器将应用于该研究 分子团簇在部分有序系统中的作用。 %%% 核磁共振光谱，NMR，是一种重要的 测定分子结构的方法。NMR方法 将发展研究固体系统的重要性， 了解沸石中的催化作用。这些都是伟大的系统 商业重要性。

This award is the starter grant increment of Dr. Chmelka's Postdoctoral Fellowship in Chemistry. The work will develop the methodology of multipolar zero-field NMR through instrumental improvements. Sample shuttling times will be reduced so as to make it possible to study systems with shorter spin-lattice relaxation times. The range of accessible dipolar couplings will be extended to 50 kHz so that solid organic compounds may be studied. The new instrumentaion will be applied to the study of molecular clusters in partially ordered systems. %%% Nuclear magnetic resonance spectroscopy, NMR, is an important method for determining molecular structure. The NMR approach will be developed to study solid systems of importance to understanding catalysis in zeolites. These are systems of great commercial importance.