The Electrochemical Polymerization of Bis-2-Pyrrolyl Conjugated Monomers to Form Highly Conducting Polymers

9307732雷诺兹这个奖项是在先进材料和加工计划中颁发的，以支持佛罗里达大学雷诺兹教授和卡特里茨基教授的合作研究。支持由化学和材料研究部提供。以取代苯、咔唑和荧烯为内部单元的新型双-2-吡咯基共轭单体将被合成并电化学聚合为高导电性聚合物。这项研究的主要目标是对氧化聚合过程中发生的电聚合和薄膜沉积过程有一个基本的了解，并指导电合成形成具有增强性能的聚合物。与现有的聚合物相比，将合成具有更高的长程有序程度的%的聚吡咯，它将具有更高的电导率和更好的环境稳定性。这些方面在静电电荷耗散和电场分级应用中是很重要的。***

9307732 Reynolds This award is made in the Advanced Materials and Processing Program in support of the collaborative research of Professors Reynolds and Katritzky at the University of Florida. Support is provided by the Divisions of Chemistry and Materials Research. Novel bis-2-pyrrolyl conjugated monomers containing substituted benzenes, carbazoles and fluorenes as internal units will be synthesized and electrochemically polymerized to highly conducting polymers. The main goal of the research is to develop a fundamental understanding of the electropolymerization and film-deposition processes that occur during oxidative polymerization and to direct the electrosynthesis to form polymers with enhanced properties. %%% Polypyrroles with higher degrees of long range order will be synthesized which will have higher electrical conductivities and improved environmental stabilities relative to presently available polymers. These aspects are important in electrostatic charge dissipation and electric field grading applications. ***