Self Assembly of One, Two and Three Dimensional Supramolecular Structures

在有机动力学项目的资助下，弗吉尼亚理工学院和州立大学的吉布森教授将开发将轮烷系统自组装成超分子结构的方法。 该方法依赖于联吡啶盐和32-冠-10醚之间的主客体关系。 一旦组装，结构将通过共价键形成而稳定。 无数的结构图案是计划和incudes线性，分支，并最终树枝状类型的架构。 这些类型的系统为光电器件、催化和质量传输介质领域的新企业带来了希望。 从轮烷和冠醚的自组装出发，设计了一类新的超分子结构。 一旦通过共价键形成组装和固定，就可以探索这些类型的结构的光电器件特性。 此外，预期它们具有催化性质，并且可以用作质量传递介质。 + 你好，我的天啊 Ý + ] $ H L + ¢ ╗ S um m m ary in for m m a t i o n ( ++++++++++++ Û ++++++++++++ ++++++++++++ ++++++++++++ D H + F t ─ +F +V 9V=rRv ─+ 9FevH─ + R:\WWUSER\TEMPLATE\NORMAL.DOT

With funding from the Organic Dynamics Program, Professor Gibson of Virginia Polytechnic Institute and State University will develop the methodology of self assembling rotaxane systems into supramolecular structures. This methodology depends on the host-guest relationship between bipyridine salts and 32-crown-10 ethers. Once assembled, the structure will be stabilized with covalent bond formation. A myriad of structural motifs is planned and incudes linear, branched and ultimately dentritic type architecture. These types of systems hold promise for new ventures in the areas of photo and electro devices, catalysis and mass transport media. A new class of supramolecular structures is planned from the self assembly of rotaxanes and crown ethers. Once assembled and fixed via covalent bond formation, these types of structures can be explored for their photo and electro device properties. Further, they are anticipated to have catayltic properties and may be used as a mass transport media. + Ûª▓ ÑOh ª' +'ª▒0 Ý + ] $ H l + ¢ ╗ S u m m a r y I n f o r m a t i o n ( ++++++++++++ Û ++++++++++++ ++++++++++++ ++++++++++++ D h + F÷t ─- +F +V 9V=rRv ─+ 9FevH─ª + R:\WWUSER\TEMPLATE\NORMAL.DOT