Preparation of Sequence-Controlled Covalent Networks (COFs) via Cross-Linking of Metal Organic Frameworks (C06)

通过新的功能性主、次连接剂，可以通过交联表面结合金属有机骨架（SURMOFs）实现三维多孔网络（SURGELs）的顺序控制制造。新的交联反应的发展（例如，通过金属催化，光诱导）以及不同设计的连接剂的使用控制了物理性质（例如，机械性质）。模块化和分层结构允许在所有三个空间方向上进行完整的几何控制。

The sequence-controlled manufacturing of three-dimensional porous networks (SURGELs) by cross-linking surface-bound metal organic frameworks (SURMOFs) will be achieved by means of new functional primary and secondary linkers. The development of new cross-linking reactions (for example, by metal catalysis, photo-induced) as well as the use of different designed linkers controls the physical properties (e.g. mechanical properties). The modular and layered structure allows the complete geometry control in all three spatial directions.