Supramolecular Recognition of Synthetic Carbon Allotropes (A07)

合成碳同素异形体(SCA)的有效非共价识别对超分子化学家提出了相当大的挑战，因为这些有机材料是部分多分散的，缺乏杂原子，并且本质上是无极或弯曲的。在A7项目中，我们将为富勒烯(具有张力碳“纳米环”；工作包1)、单壁碳纳米管(具有动态共价大环；工作包2)和石墨烯边缘缺陷(具有双酰胺分子线；工作包3)的超分子识别和功能化开发创新的概念和化合物。

The effective non-covalent recognition of Synthetic Carbon Allotropes (SCAs) poses a considerable challenge to the supramolecular chemist, because these organic materials are partially polydisperse, lack heteroatoms and are inherently apolar or curved. In project A7, we will develop innovative concepts and compounds for the supramolecular recognition and functionalization of fullerenes (with strained carbon “nanohoops”; work package 1), single-walled carbon nanotubes (with dynamic covalent macrocycles; work package 2) and graphene edge defects (with bis-amidinium molecular wires; work package 3).