ansa-Compounds of Main-Group Elements

在键激活过程中，特别是在均相催化中，有几个s-嵌段化合物被使用的例子。所应用的配合物几乎都表现为氮基配体体系。与此相反，我们采用了一种方法，使用环戊二烯化合物的s-嵌段金属，特别是2族元素的茂金属。在本后续课题中，将研究不同的茂镁烯类和茂镁烯类在脱氢偶联反应、小分子活化和配位化学中的应用。

There are several examples of s-block compounds being used in bond activation processes, especially in homogeneous catalysis. The applied complexes exhibit almost always nitrogen-based ligand systems. In contrast to this, we take an approach to use cyclopentadienyl compounds of s-block metals, in particular metallocenes of group 2 elements.In the course of this follow-up proposal, different magnesocenes and magnesocenophanes will be investigated with regards to their application in dehydrocoupling reactions, small molecules activation and coordination chemistry.