Synthese und Eigenschaften von supramolekularen zylindrischen Strukturen aus Blockcopolymeren mit organometallischen Baueinheiten

在这个建议中，概述了一个计划，其目的是发展含金属嵌段共聚物的合成和溶液自组装。该计划将开发新型的圆柱形纳米结构，并探索其作为纳米级线状结构的应用。该材料将联合收割机结合由聚（二茂铁基硅烷）（PFS）嵌段中的金属原子的存在赋予纳米结构的核心的新的功能性质。该跨学科项目将涉及合成聚合物化学，详细的表征和物理性质的研究。然后将探索这些材料在纳米科学中的应用，例如在器件中和作为抗蚀剂。

In this proposal a plan is outlined which aims to develop the synthesis and solution selfassembly of metal-containing block copolymers. The program will develop novel cylindrical nanostructures and explore their applications as nanosize wire-like architectures. The materials will combine the novel functional properties imparted by the presence of metal atoms in the poly(ferrocenylsilane) (PFS) block to the core of the nanostructure. The interdisciplinary project will involve synthetic polymer chemistry, detailed characterization and studies of physical properties. Applications of the materials in nanoscience, for example in devices and as etch resists, will then be explored.