Co-operative Hydridization of Electron-Transfer Processes in Surface-Catalyst-Biochemical Systems

本研究项目旨在通过有机反应与合成、电化学催化、生物功能等不同领域的研究人员之间的合作联盟，实现电子转移过程的合作杂交。与电子转移过程相关的研究人员与不同领域的研究人员交流了他们的概念。一次是第18届EOC研讨会(名古屋，1995年6月)，另一次是当前合作研究(A)的公开研讨会(A)(名古屋，1995年11月)。本研究与三个项目有关：(1)通过表面修饰发展杂化电子转移系统。(2)催化剂-电极复合体系的分子转化；(3)生物反应和电极反应相结合的分子转化。这些项目与电子转移过程有关，它们的合作杂交可能导致选择性转化和功能放大。例如，通过金属络合物和芳香族化合物等电子转移媒介实现了对底物的高选择性转化。含有酶的复合电极已被证明是一种良好的选择性传感器。电子转移过程的控制已经取得了相当大的进展，合作杂交的基本概念已经形成。

The present research project was organized to achieve the co-operative hybridization of electron-transfer processes by co-operative unions between researchers of various fields such as organic reaction and synthesis, electrochemistry catalysis, and biological functions. The researchers relating electron-transfer processes exchanged their concept with researchers of different fields. One meeting was the 18th EOC Symposium (Nagoya, June, 1995) and the other was the open symposium of present co-operative research (A) (Nagoya, November, 1995).The present research is related to three projects : (1) developments of hybridized electron-transfer systems by surface modifications. (2) molecule transformations by catalyst-electrode composite systems, and (3) molecular transformations by combinations of biological and electrode reactions. These projects are related to electron transfer processes and their co-operative hybridization could lead to selective transformations and function amplifications. For example, highly selective transformations of substrates were achieved by electron transfer mediators such as metal complexes and aromatic compounds. Composite electrodes containing enzymes have been shown to be a good selective sensor. Controlles of electron transfer processes have been achieved considerably and a basic concept for co-operative hybridization could be developed.