New Material Transformation under Unusual Reaction Conditions

1高压反应：合成具有新型分子识别性能的超分子化合物，高压促进的亲核取代芳香胺的合成，高压促进酶催化核酸的转化，肌钙蛋白的环加成反应，β-酮酯的E-Z异构化和Michael加成反应等几种基团的转化。2超声波反应：超声波对固相有机反应的影响，氟尿嘧啶衍生物的超声反应活化及其作为前体的应用，有机分子在水介质中的超声波作用，氧的超声活化及其机理研究，有机分子的超声波氟化，有机化合物在固态中的选择性转化。3闪速真空热解：在气相中高压下产生的卡宾和硝烯的反应性，合成新型的环状有机硅和有机锗化合物。4等离子体化学：有机材料的选择性转化，自由基物种的产生，功能聚合物的表面处理，过氧自由基在固态中的结构和反应性。

1 High Pressue Reactions : Synthesis of suprampolecular compounds having a novel molecular recognition property, synthesis of aromatic amines via high-pressure promoted nucleophilic aromatic substitution, transformation of nucleic acids by high-pressure promoted enzyme catalysis, cycloaddition reactions of troponoids, several ogranic functional group transformation such as E-Z isomerization and Michael addition reactions of beta-ketoesters.2 Ultrasonic Reactios : Effect of ultrasonics on the solid state organic reactions, ultrasonic reaction activation of fluorouracil derivatives and their use as prodrags, ultrasonic of organic molecules in aqueous media, ultrasonic activation of oxygen and its mechanistic investigation, ultrasonic fluorination of organic molecules, selective transformation of organic compounds in the solid state.3 Flash Vacuum Pyrolysis : Reactivity of carbenes and nitrenes generated at high pressure in vapor phase, synthesis of novel cyclic organosilicon and organogermanium compounds.4 Plasma Chemistry : Selective transformation of organic materials, generation of radical species, surface treatment of functional polymers, structure and reactivity of peroxyl radicals in the solid state.