Pational Control of Dimensional Structures of Metal-Assembled Ccmplexes

我们进行了合理控制金属组装配合物的空间结构的研究。这些配合物是由金属如银、钯、铂、铜、钴、铁、金、钌和镍与配体如卤素、双噻吩基乙烯、芘、氰基、环戊二烯基和胺之间的结合制备的。所制备的金属配合物具有三维、二维和一维可控结构，并研究了它们的化学和物理性质以及它们的化学和物理功能。为了制备这些金属配合物，合成了新的配体。

We have carried out research for rational control of dimensional structures of metal-assembled complexes. The complexes were prepared with combination between metals such as silver, palladium, platinum, copper, cobalt, iron, gold, ruthenium and nickel and ligands such as halogen, bisthienylethenes, pyrenes, cyano group, cyclopentadienyls and amines. The prepared metal complexes had 3-, 2-, and one-dimensionally controlled structures, and their chemical and physical properties and their chemical and physical functions were studied. In order to prepare these metal complexes, new ligands were synthesized.Electrically conducting, o