Development of nanoporous metal coordination compounds for resolution of environment and energy issues

近年来，我们发现的多孔复合物由于其有趣的结构，更重要的是由于其在气体储存，分离和催化方面的潜在应用而得到了广泛的研究。本项目合成了新型多孔复合物，并评价了多孔复合物的氢吸附性能和产氢催化活性，以构建清洁能源系统。氢吸附性能取决于节点金属，具有小孔径的多孔复合物显示出高的氢吸附能力。在钌基和铑基多孔配合物中，在现有的助催化剂下表现出了制氢催化活性。

Porous complexes which we found have been extensively studied in recent years because of their intriguing structures and, more importantly, for their potential applications in gas storage, separation, and catalysis. In this project, we have synthesized the novel porous complexes and evaluated hydrogen adsorption properties and the hydrogen production-catalytic activities of the porous complexes in order to construct a clean energy system. The hydrogen adsorption properties depended upon the node-metals, and the porous complexes having small pore size showed a highly hydrogen-adsorption capability. In the Ru- and Rh-based porous complexes showed a hydrogen production-catalytic activity under the existing co-catalysts.