Application of the internal magneticfieldof nano-size coordinati on space to create new reaction fields.
Application of the internal magneticfieldof nano-size coordinati on space to create new reaction fields.
批准号:
19710079
负责人:
AKITA Motoko
金额:
$2.46万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2007
资助国家:
日本
项目状态:
已结题
起止时间:
2007 至 2009
中文摘要
合成了一系列层状分子基磁体,并对其晶体结构和磁性能进行了研究。三氮氧自由基(TRs)具有三个配位,与过渡金属离子形成2:3的配合物TR_2M(II)_3。通过水热合成D-、L-和DL-氨基酸与几种过渡金属的化合物,得到了具有铁磁性、反铁磁性和弱铁磁性的分子基磁体。
英文摘要
A series of layered molecular-based magnets were synthesized, and their crystal structure and magnetic properties were studied. Trisnitroxide radicals(TRs) have three ligating sites and give the 2:3 complex TR_2M(II)_3 with transition metal ions. Hydrothermal synthesis of D-, L-, and DL-amino acid with several transition metals gave a variety of molecular-based magnets which shows ferromagneism, antiferromagnetism and weak-ferromagnetism.
期刊论文(0)
专著(0)
科研奖励(0)
会议论文
Synthesis, Crystal Structures, and Propcrties of Molecular Squares Displaying Hydrogen and π-π Bonded Networks
显示氢和 π-π 键合网络的分子方的合成、晶体结构和性质
DOI:
--
发表时间:
2009
期刊:
Crystal Growth & Design 9
影响因子:
--
作者:
[K.Kumagai, M.Akita-Tanaka, S.Kawata, K.Inoue, C.Kepert, M.Kurmoo]
通讯作者:
M.Kurmoo
Attempts toward Asymmetric Syntheses with No Chemical and Physical Chiral Sources
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批准号:25620065
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项目类别:Grant-in-Aid for Challenging Exploratory Research
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资助金额:$2.58万
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财政年份:2013
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负责人:AKITA Motoko
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依托单位:
High functionalization of nano-size coordination space based on itsinternal magnetic field for a specific reaction in the cavity
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批准号:22710089
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项目类别:Grant-in-Aid for Young Scientists (B)
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资助金额:$2.5万
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财政年份:2010
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负责人:AKITA Motoko
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依托单位:
海外基金