The construction and durability enhancement of alpha-phthalocyanine catalytic layer with a superior effect as over potential reducing at fuel cell cathode
The construction and durability enhancement of alpha-phthalocyanine catalytic layer with a superior effect as over potential reducing at fuel cell cathode
批准号:
20550126
负责人:
TAKASE Satoko
金额:
$3.41万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2008
资助国家:
日本
项目状态:
已结题
起止时间:
2008 至 2010
中文摘要
采用将金属酞菁单体溶解于有机酸溶液中的中和沉积方法,将化学稳定性较好的金属酞菁催化剂高度分散在气体扩散碳电极上。具有α相晶体结构的FePc、CoPc表现出较强的氧还原活性。此外,不同种类MPcs的混合对催化活性的提高也有影响。
英文摘要
The chemical stable metal phthalocyanines (MPcs) catalysts were highly dispersed on the gas diffusion carbon electrodes by neutralization deposition methods which used monomeric MPcs dissolved in organic acid solution. The FePc, CoPc with α phase crystal structures showed high activities toward oxygen reduction reaction rather than other MPcs. Moreover, the mix of difference kind of MPcs affect to enhance catalytic activities.
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DOI:
10.1149/1.2981935
发表时间:
2008-10
期刊:
影响因子:
--
作者:
[T. Iwanaga;Satoko Takase;Y. Shimizu]
通讯作者:
T. Iwanaga;Satoko Takase;Y. Shimizu
Preparation of Amperometric Hydrogen-Phosphate Ion Sensor Based on Perovskite-Type Oxide Thick-Film by EPD Process
EPD工艺制备钙钛矿型氧化物厚膜电流型氢磷酸离子传感器
DOI:
--
发表时间:
2010
期刊:
Electrochemistry 78
影响因子:
--
作者:
[S.Takase, T.Matsumoto, Y.Shimizu]
通讯作者:
Y.Shimizu
Oxygen Reduction Properties of α-metal phthalocyanine Prepared by Electrophoretic Deposition Method
电泳沉积法制备α-金属酞菁的氧还原性能
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[G. X. Liu, W. Guo, S. Nishihara, X. M. Ren, 高瀬聡子]
通讯作者:
高瀬聡子
Preparation of Perovskite-Type Oxide Fine Powder and Thin-Film by Polymer Precursor Method
聚合物前驱体法制备钙钛矿型氧化物细粉及薄膜
DOI:
--
发表时间:
2008
期刊:
影响因子:
--
作者:
[Yoshiko SASAKI, Ryohei FUKAE, Ken SASAKI, 高瀬聡子]
通讯作者:
高瀬聡子
Electrocatalytic Properties of Metallophthalocyanines Films Prepared by Electrophoretic Deposition Method
电泳沉积法制备金属酞菁薄膜的电催化性能
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[G. X. Liu, X. L. Xu, Y. Y. Xu, S. Nishihara, X. M. Ren, 高瀬聡子]
通讯作者:
高瀬聡子
共 7 条
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