Development of Innovative Molecular Transformations Via Cationic Rhodacycles as Active Species

本研究详细探讨了各种高活性阳离子红戴环的生成方法，并开发了许多以这些中间体为活性物质的新型催化剂。这些发展的催化剂被扩展到不对称催化剂，能够构建轴向、平面、螺旋和多中心手性，并合成功能性有机材料。“阳离子环化学”由此成立。

In this research, the method of generating various highly reactive cationic rhodacycles was examined in detail , and many novel catalyses which involve these intermediates as active species were developed. These developed catalyses were expanded to the asymmetrical catalyses that are able to construct axial, planar, helical, and multiple central chiralities, and syntheses of functional organic materials. Thus, "chemistry of cationic rhodacycles " was established.